696668

Nickel(II) chloride ethylene glycol dimethyl ether complex

98%

Manufacturer: Sigma Aldrich

CAS Number: 29046-78-4

Synonym(S): Dichloro(dimethoxyethane)nickel, NiCl2 glyme

Select a Size

Pack Size SKU Availability Price
1 G 696668-1-G In Stock ₹ 5,130.00
5 G 696668-5-G In Stock ₹ 14,340.00

696668 - 1 G

₹ 5,130.00

In Stock

Quantity

1

Base Price: ₹ 5,130.00

GST (18%): ₹ 923.40

Total Price: ₹ 6,053.40

Assay

98%

form

powder

reaction suitability

core: nickelreagent type: catalyst

mp

>300 °C

SMILES string

Cl[Ni]Cl.COCCOC

InChI

1S/C4H10O2.2ClH.Ni/c1-5-3-4-6-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2

InChI key

OCMNCWNTDDVHFK-UHFFFAOYSA-L

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Description

  • Application: Nickel(II) chloride ethylene glycol dimethyl ether complex can be used:As a catalyst for the borylation of racemic benzylic chloride to synthesize enantioenriched benzylic boronic esters.[1]As a promoter for the trifluoromethylation of alkyl iodides to synthesize broad range of alkyl-CF3 compounds.[2]For the synthesis of nickel bis(benzimidazol-2-ylidene) pincer complexes which can be used for electrocatalytic reduction of CO2 to CO.[3]As a Lewis acid catalyst for C-acylation β-ketoesters through photoactivation by visible light.[4]

SAFETY INFORMATION

Pictograms

GHS02,GHS06,GHS08,GHS09

Signal Word

Danger

Hazard Statements

H261,H301,H315,H319,H334,H350,H400

Precautionary Statements

P202 - P231 + P232 - P273 - P301 + P310 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Water-react 2

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

696668

98%...


Assay:
98%

form:
powder

reaction suitability:
core: nickelreagent type: catalyst

mp:
>300 °C

SMILES string:
Cl[Ni]Cl.COCCOC

InChI:
1S/C4H10O2.2ClH.Ni/c1-5-3-4-6-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2

InChI key:
OCMNCWNTDDVHFK-UHFFFAOYSA-L

Img

Sigma Aldrich

696676

--


Assay:
__

form:
powder

reaction suitability:
core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

mp:
__

SMILES string:
Cl[Pd]Cl.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4

InChI:
1S/C27H26P2.2ClH.Pd/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2

InChI key:
LDFBXJODFADZBN-UHFFFAOYSA-L

Img

Supelco

69669

analytical standard...


Assay:
≥98.0% (HPLC)

form:
__

reaction suitability:
__

mp:
100-102 °C (lit.)

SMILES string:
CN(C)c1ccc(cc1)C(c2ccccc2)c3ccc(cc3)N(C)C

InChI:
1S/C23H26N2/c1-24(2)21-14-10-19(11-15-21)23(18-8-6-5-7-9-18)20-12-16-22(17-13-20)25(3)4/h5-17,23H,1-4H3

InChI key:
__

Img

Sigma Aldrich

696722

97%...


Assay:
97%

form:
solid

reaction suitability:
__

mp:
__

SMILES string:
Brc1c(Br)c(C=O)sc1C=O

InChI:
1S/C6H2Br2O2S/c7-5-3(1-9)11-4(2-10)6(5)8/h1-2H

InChI key:
UIIQKZFRHPLSLU-UHFFFAOYSA-N