Copper(I) cyanide di(lithium chloride) complex solution
in anhydrous tetrahydrofuran
Manufacturer: Sigma Aldrich
Synonym(S): Copper(I) cyanide di(lithium chloride)
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 50 ML | 697257-50-ML | In Stock | ₹ 15,685.43 |
697257 - 50 ML
In Stock
Quantity
1
Base Price: ₹ 15,685.43
GST (18%): ₹ 2,823.377
Total Price: ₹ 18,508.807
form
liquid
Quality Level
100
reaction suitability
core: copperreagent type: catalyst
concentration
in anhydrous tetrahydrofuran
density
0.999 g/mL at 25 °C
SMILES string
[Li]Cl.[Li]Cl.[Cu]C#N
InChI
1S/CN.2ClH.Cu.2Li/c1-2;;;;;/h;2*1H;;;/q;;;;2*+1/p-2
InChI key
QGXKBLXNBYNHBV-UHFFFAOYSA-L
Related Products
Description
- Application: Copper(I) cyanide di(lithium chloride) complex can be used for the synthesis of organocopper(I) reagents by transmetalation with organozinc[1][2] and Grignard reagents.[3] It is also a useful precursor to prepare organocuprate(I) reagents.
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
EUH019
WGK
WGK 2
Flash Point(F)
Solvent
Flash Point(C)
Solvent
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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form: liquid
Quality Level: 100
reaction suitability: core: copperreagent type: catalyst
concentration: in anhydrous tetrahydrofuran
density: 0.999 g/mL at 25 °C
SMILES string: [Li]Cl.[Li]Cl.[Cu]C#N
InChI: 1S/CN.2ClH.Cu.2Li/c1-2;;;;;/h;2*1H;;;/q;;;;2*+1/p-2
InChI key: QGXKBLXNBYNHBV-UHFFFAOYSA-L
form: crystals
Quality Level: 200
reaction suitability: core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst
concentration: __
density: __
SMILES string: [Pd].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12
InChI: 1S/4C18H15P.Pd/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;
InChI key: NFHFRUOZVGFOOS-UHFFFAOYSA-N
form: __
Quality Level: 100
reaction suitability: __
concentration: __
density: __
SMILES string: O=C(CC(O)CCC1=CC(OC)=C(O)C=C1)CCC2=CC(OC)=C(O)C=C2
InChI: 1S/C21H26O6/c1-26-20-11-14(5-9-18(20)24)3-7-16(22)13-17(23)8-4-15-6-10-19(25)21(12-15)27-2/h5-6,9-12,16,22,24-25H,3-4,7-8,13H2,1-2H3
InChI key: RSAHICAPUYTWHW-UHFFFAOYSA-N
