697575
(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate
Manufacturer: Sigma Aldrich
CAS Number: 866641-66-9
Synonym(S): JohnPhos Au(MeCN)SbF6
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 250 MG | 697575-250-MG | In Stock | ₹ 11,500.00 |
| 1 G | 697575-1-G | In Stock | ₹ 46,142.70 |
697575 - 250 MG
In Stock
Quantity
1
Base Price: ₹ 11,500.00
GST (18%): ₹ 2,070.00
Total Price: ₹ 13,570.00
form
solid
Quality Level
100
reaction suitability
core: goldreagent type: catalyst
mp
198-203 °C (D)
SMILES string
[Au+].CC#N.F[Sb-](F)(F)(F)(F)F.CC(C)(C)P(c1ccccc1-c2ccccc2)C(C)(C)C
InChI
1S/C20H27P.C2H3N.Au.6FH.Sb/c1-19(2,3)21(20(4,5)6)18-15-11-10-14-17(18)16-12-8-7-9-13-16;1-2-3;;;;;;;;/h7-15H,1-6H3;1H3;;6*1H;/q;;+1;;;;;;;+5/p-6
InChI key
ADQOZROJMVWPRI-UHFFFAOYSA-H
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences (Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate | 866641-66-9 | MFCD11045449 | 1G | Sigma Aldrich Fine Chemicals Biosciences | ₹ 39,514.17 | |
 | Sigma Aldrich Fine Chemicals Biosciences (Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate | 866641-66-9 | MFCD11045449 | 250MG | Sigma Aldrich Fine Chemicals Biosciences | ₹ 14,673.54 | |
 | 866641-66-9 | (Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate | A2B Chem | ₹ 7,272.60 - ₹ 19,422.12 |
Related Products
Description
- General description: (Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate is a phosphine ligated gold(I) complex. It is used as a catalyst in a domino reaction to form C–C, C–N, and C–O bonds due to the ease with which it can activate C=C and C≡C bonds, thus allowing for unique rearrangements or reactions with various nucleophiles. Gold catalysis provides an excellent method to construct complex chemical architectures in a mild manner that would be difficult to achieve using other reaction paradigms.
- Application: Gold Catalysts — 21st Century ′Gold Rush′
SAFETY INFORMATION
Pictograms
Signal Word
Warning
Hazard Statements
Precautionary Statements
P261 - P264 - P271 - P273 - P301 + P312 - P304 + P340 + P312
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Compare Similar Items
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form: solid
Quality Level: 100
reaction suitability: core: goldreagent type: catalyst
mp: 198-203 °C (D)
SMILES string: [Au+].CC#N.F[Sb-](F)(F)(F)(F)F.CC(C)(C)P(c1ccccc1-c2ccccc2)C(C)(C)C
InChI: 1S/C20H27P.C2H3N.Au.6FH.Sb/c1-19(2,3)21(20(4,5)6)18-15-11-10-14-17(18)16-12-8-7-9-13-16;1-2-3;;;;;;;;/h7-15H,1-6H3;1H3;;6*1H;/q;;+1;;;;;;;+5/p-6
InChI key: ADQOZROJMVWPRI-UHFFFAOYSA-H
form:
solid
Quality Level:
100
reaction suitability:
core: goldreagent type: catalyst
mp:
198-203 °C (D)
SMILES string:
[Au+].CC#N.F[Sb-](F)(F)(F)(F)F.CC(C)(C)P(c1ccccc1-c2ccccc2)C(C)(C)C
InChI:
1S/C20H27P.C2H3N.Au.6FH.Sb/c1-19(2,3)21(20(4,5)6)18-15-11-10-14-17(18)16-12-8-7-9-13-16;1-2-3;;;;;;;;/h7-15H,1-6H3;1H3;;6*1H;/q;;+1;;;;;;;+5/p-6
InChI key:
ADQOZROJMVWPRI-UHFFFAOYSA-H
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