698253

Tris(3,5-dimethylphenyl)phosphine

96%

Manufacturer: Sigma Aldrich

CAS Number: 69227-47-0

Synonym(S): Tri-3,5-xylylphosphine

Select a Size

Pack Size SKU Availability Price
1 G 698253-1-G In Stock ₹ 8,129.58

698253 - 1 G

₹ 8,129.58

In Stock

Quantity

1

Base Price: ₹ 8,129.58

GST (18%): ₹ 1,463.324

Total Price: ₹ 9,592.904

Quality Level

100

Assay

96%

form

powder

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand

mp

160-165 °C

functional group

phosphine

SMILES string

Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3cc(C)cc(C)c3

InChI

1S/C24H27P/c1-16-7-17(2)11-22(10-16)25(23-12-18(3)8-19(4)13-23)24-14-20(5)9-21(6)15-24/h7-15H,1-6H3

InChI key

XRALRSQLQXKXKP-UHFFFAOYSA-N

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Description

  • Application: Catalyst for:Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enonesHighly selective rhodium-catalyzed hydrogenation reactionsClassical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenesUsed for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanesUsed for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H302

Hazard Classifications

Acute Tox. 4 Oral

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

698253

96%...


Quality Level:
100

Assay:
96%

form:
powder

reaction suitability:
reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand

mp:
160-165 °C

functional group:
phosphine

SMILES string:
Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3cc(C)cc(C)c3

InChI:
1S/C24H27P/c1-16-7-17(2)11-22(10-16)25(23-12-18(3)8-19(4)13-23)24-14-20(5)9-21(6)15-24/h7-15H,1-6H3

InChI key:
XRALRSQLQXKXKP-UHFFFAOYSA-N

Img

Sigma Aldrich

698261

97%...


Quality Level:
100

Assay:
97%

form:
powder

reaction suitability:
reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand

mp:
174-179 °C

functional group:
phosphine

SMILES string:
COc1c(C)cc(cc1C)P(c2cc(C)c(OC)c(C)c2)c3cc(C)c(OC)c(C)c3

InChI:
1S/C27H33O3P/c1-16-10-22(11-17(2)25(16)28-7)31(23-12-18(3)26(29-8)19(4)13-23)24-14-20(5)27(30-9)21(6)15-24/h10-15H,1-9H3

InChI key:
BDGUINGZRGNLPD-UHFFFAOYSA-N

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