700045

(2-Butenyl)chloropalladium dimer

≥97%

Manufacturer: Sigma Aldrich

CAS Number: 12081-22-0

Synonym(S): Bis[(1,2,3-η)-2-buten-1-yl]di-μ-chlorodi-palladiumdi-π-crotylpalladium chloride, Di-π-Crotylpalladium chloride, Di-2-butenyldipalladium dichloride, Dichlorobis(1-methylallyl)dipalladium

Select a Size

Pack Size SKU Availability Price
1 G 700045-1-G In Stock ₹ 25,130.40

700045 - 1 G

₹ 25,130.40

In Stock

Quantity

1

Base Price: ₹ 25,130.40

GST (18%): ₹ 4,523.472

Total Price: ₹ 29,653.872

Quality Level

100

Assay

≥97%

form

powder

reaction suitability

core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

mp

133-140 °C

SMILES string

C\C=C\C[Pd]Cl.C\C=C\C[Pd]Cl

InChI

1S/2C4H7.2ClH.2Pd/c2*1-3-4-2;;;;/h2*3-4H,1H2,2H3;2*1H;;/q;;;;2*+1/p-2/b2*4-3+;;;;

InChI key

NTFUUQYNUUTALG-HYTOEPEZSA-L

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Description

  • Application: Catalyst for:Enantioselective elimination of palladium hydrideNon-covalent anchoring of catalysts to silica supportsAllylations of cyanoacetatesEnantioselective nucleophilic substitutionsReactant for:Allylic alkylation reactionsPreparation of phosphane-functionalized carbosilane dendrimers

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Show Difference

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Sigma Aldrich

700045

≥97%...


Quality Level:
100

Assay:
≥97%

form:
powder

reaction suitability:
core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

mp:
133-140 °C

SMILES string:
C\C=C\C[Pd]Cl.C\C=C\C[Pd]Cl

InChI:
1S/2C4H7.2ClH.2Pd/c2*1-3-4-2;;;;/h2*3-4H,1H2,2H3;2*1H;;/q;;;;2*+1/p-2/b2*4-3+;;;;

InChI key:
NTFUUQYNUUTALG-HYTOEPEZSA-L

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Sigma Aldrich

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Quality Level:
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Assay:
>99% (TLC)

form:
powder

reaction suitability:
__

mp:
__

SMILES string:
__

InChI:
1S/C27H44O2/c1-17(2)7-6-8-18(3)21-9-10-22-25-23(12-14-27(21,22)5)26(4)13-11-20(28)15-19(26)16-24(25)29/h16-18,20-23,25,28H,6-15H2,1-5H3/t18-,20+,21?,22+,23+,25+,26+,27-/m1/s1/i1D3,2D3,17D

InChI key:
YIKKMWSQVKJCOP-YMQSFMNJSA-N

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Sigma Aldrich

700047P

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Assay:
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form:
powder

reaction suitability:
__

mp:
__

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__

InChI:
__

InChI key:
__

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Sigma Aldrich

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Quality Level:
100

Assay:
__

form:
liquid

reaction suitability:
__

mp:
__

SMILES string:
__

InChI:
__

InChI key:
__