701998

[1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II)

98%

Manufacturer: Sigma Aldrich

CAS Number: 917511-90-1

Synonym(S): PdCl2(dcypf)

Select a Size

Pack Size SKU Availability Price
250 MG 701998-250-MG In Stock ₹ 6,238.20
1 G 701998-1-G In Stock ₹ 23,731.80

701998 - 250 MG

₹ 6,238.20

In Stock

Quantity

1

Base Price: ₹ 6,238.20

GST (18%): ₹ 1,122.876

Total Price: ₹ 7,361.076

Quality Level

100

Assay

98%

form

powder

reaction suitability

core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

mp

294-300 °C

storage temp.

−20°C

SMILES string

[Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(C2CCCCC2)C3CCCCC3.[CH]4[CH][CH][C]([CH]4)P(C5CCCCC5)C6CCCCC6

InChI

1S/2C17H26P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*7-8,13-16H,1-6,9-12H2;2*1H;;/q;;;;;+2/p-2

InChI key

HRAMBTUEZQOQRK-UHFFFAOYSA-L

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Description

  • Application: 1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II) or (Pd(dcpf)Cl2) can be used as a catalyst in the synthesis of: α, β-unsaturated amides by hydroaminocarbonylation of alkynes with tertiary amines.[1]Quinazoline derivatives via Suzuki-Miyaura coupling reaction between of quinazolines containing unprotected NH2 group and arylboronic acids.[2] α-aryl carbonyl compounds by α-arylation of ketones with aryl chlorides and aryl bromides.[3]

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Quality Level:
100

Assay:
98%

form:
powder

reaction suitability:
core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

mp:
294-300 °C

storage temp.:
−20°C

SMILES string:
[Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(C2CCCCC2)C3CCCCC3.[CH]4[CH][CH][C]([CH]4)P(C5CCCCC5)C6CCCCC6

InChI:
1S/2C17H26P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*7-8,13-16H,1-6,9-12H2;2*1H;;/q;;;;;+2/p-2

InChI key:
HRAMBTUEZQOQRK-UHFFFAOYSA-L

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