RuCl(p-cymene)[(S,S)-Ts-DPEN]
Manufacturer: Sigma Aldrich
CAS Number: 192139-90-5
Synonym(S): [N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-ruthenium
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 703915-100-MG | In Stock | ₹ 4,340.10 |
| 500 MG | 703915-500-MG | In Stock | ₹ 13,297.80 |
703915 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 4,340.10
GST (18%): ₹ 781.218
Total Price: ₹ 5,121.318
form
solid
Quality Level
100
optical activity
[α]20/D +178°, c = 0.5 in chloroform
mp
>175 °C
storage temp.
2-8°C
SMILES string
CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@H]([C@@H](N)c3ccccc3)c4ccccc4
InChI
1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m0.../s1
InChI key
AZFNGPAYDKGCRB-XCPIVNJJSA-M
Other Options
Description
- General description: RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium, which can be used for the asymmetric transfer hydrogenation of a variety of imines.[1]
- Application: Takasago Ligands and Complexes for Asymmetric Reactions
- Legal Information: Sold in collaboration with Takasago for research purposes only. WO9720789
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
form: solid
Quality Level: 100
optical activity: [α]20/D +178°, c = 0.5 in chloroform
mp: >175 °C
storage temp.: 2-8°C
SMILES string: CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@H]([C@@H](N)c3ccccc3)c4ccccc4
InChI: 1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m0.../s1
InChI key: AZFNGPAYDKGCRB-XCPIVNJJSA-M
form: powder
Quality Level: 100
optical activity: __
mp: 215-219 °C
storage temp.: __
SMILES string: OC(=O)c1ccc(cc1F)C#N
InChI: 1S/C8H4FNO2/c9-7-3-5(4-10)1-2-6(7)8(11)12/h1-3H,(H,11,12)
InChI key: KEJMSTJTAWACNI-UHFFFAOYSA-N
form: powder
Quality Level: 100
optical activity: __
mp: 93-98 °C
storage temp.: __
SMILES string: Brc1cccnc1C#N
InChI: 1S/C6H3BrN2/c7-5-2-1-3-9-6(5)4-8/h1-3H
InChI key: HCOPIUVJCIZALB-UHFFFAOYSA-N
