739103

Ru-MACHO®

Manufacturer: Sigma Aldrich

CAS Number: 1295649-40-9

Synonym(S): Carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethyl]amino}ruthenium(II), {Bis[2-(diphenylphosphino)ethyl]amine}carboynlchlorohydridoruthenium(II)

Select a Size

Pack Size SKU Availability Price
250 MG 739103-250-MG In Stock ₹ 9,790.20
1 G 739103-1-G In Stock ₹ 21,990.00
5 G 739103-5-G In Stock ₹ 91,086.60

739103 - 250 MG

₹ 9,790.20

In Stock

Quantity

1

Base Price: ₹ 9,790.20

GST (18%): ₹ 1,762.236

Total Price: ₹ 11,552.436

form

solid

Quality Level

100

reaction suitability

core: rutheniumreagent type: catalyst

mp

260-290 °C

SMILES string

Cl[Ru].[C-]#[O+].C(CP(c1ccccc1)c2ccccc2)NCCP(c3ccccc3)c4ccccc4

InChI

1S/C28H29NP2.CO.ClH.Ru/c1-5-13-25(14-6-1)30(26-15-7-2-8-16-26)23-21-29-22-24-31(27-17-9-3-10-18-27)28-19-11-4-12-20-28;1-2;;/h1-20,29H,21-24H2;;1H;/q;;;+1/p-1

InChI key

GQFWSAKCCNATEV-UHFFFAOYSA-M

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Description

  • Application: <ul><li><strong>Dehydrogenative Intramolecular Macrolactonization:</strong> Ru-MACHO catalyst is applied in dehydrogenative intramolecular macrolactonization of dihydroxy compounds, demonstrating its efficiency in organic synthesis with potential implications for pharmaceutical synthesis (Jamdade et al., 2022).</li><li><strong>Acceptorless Dehydrogenation of Methanol:</strong> Employing Ru-MACHO catalyst in the acceptorless dehydrogenation of methanol to produce carbon monoxide and hydrogen, this process highlights Ru-MACHO′s capability in catalytic transformations and green chemistry applications (Kaithal et al., 2021).</li><li><strong>Precapture and Hydrogenation of CO2:</strong> A study on the heterogenized Ru-MACHO catalytic systems for pre-capture and hydrogenation of CO2 into methanol, underscoring the catalyst′s potential in sustainable chemical processes (Szego et al., 2023).</li><li><strong>Pressure-dependent Hydrogenative Depolymerization:</strong> The Ru-MACHO catalyst is used for highly selective pressure-dependent hydrogenative depolymerization of polybutylene succinate, demonstrating the catalyst′s versatility in polymer processing and chemical recycling (Johnson et al., 2024).</li> </ul>
  • Legal Information: Sold in collaboration with Takasago for research purposes only. Ru-MACHO is a registered trademark of Takasago Intl. Corp. PCT/JP2010-004301.

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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form:
solid

Quality Level:
100

reaction suitability:
core: rutheniumreagent type: catalyst

mp:
260-290 °C

SMILES string:
Cl[Ru].[C-]#[O+].C(CP(c1ccccc1)c2ccccc2)NCCP(c3ccccc3)c4ccccc4

InChI:
1S/C28H29NP2.CO.ClH.Ru/c1-5-13-25(14-6-1)30(26-15-7-2-8-16-26)23-21-29-22-24-31(27-17-9-3-10-18-27)28-19-11-4-12-20-28;1-2;;/h1-20,29H,21-24H2;;1H;/q;;;+1/p-1

InChI key:
GQFWSAKCCNATEV-UHFFFAOYSA-M

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OC(=O)CCc1ccccc1I

InChI:
1S/C9H9IO2/c10-8-4-2-1-3-7(8)5-6-9(11)12/h1-4H,5-6H2,(H,11,12)

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POJTZKMVSQVKNR-UHFFFAOYSA-N

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CC(C)(C)OC(=O)Nc1ccnc(Cl)c1C(O)=O

InChI:
1S/C11H13ClN2O4/c1-11(2,3)18-10(17)14-6-4-5-13-8(12)7(6)9(15)16/h4-5H,1-3H3,(H,15,16)(H,13,14,17)

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UFNXHDCOFAGXCX-UHFFFAOYSA-N

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mp:
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SMILES string:
__

InChI:
__

InChI key:
__