746339

Dichlorotriphenylphosphine[bis(2-(ethylthio)ethyl)amine]ruthenium(II)

97%

Manufacturer: Sigma Aldrich

CAS Number: 1462397-86-9

Synonym(S): Ru-SNS catalyst

Select a Size

Pack Size SKU Availability Price
100 MG 746339-100-MG In Stock ₹ 6,082.80
500 MG 746339-500-MG In Stock ₹ 25,763.10

746339 - 100 MG

₹ 6,082.80

In Stock

Quantity

1

Base Price: ₹ 6,082.80

GST (18%): ₹ 1,094.904

Total Price: ₹ 7,177.704

Quality Level

100

Assay

97%

form

solid

reaction suitability

core: rutheniumreagent type: catalyst

greener alternative product characteristics

CatalysisLearn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

300-310 °C

greener alternative category

Aligned,

SMILES string

CCSCCN([H])CCSCC.Cl[Ru]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

InChI

1S/C18H15P.C8H19NS2.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-10-7-5-9-6-8-11-4-2;;;/h1-15H;9H,3-8H2,1-2H3;2*1H;/q;;;;+2/p-2

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Description

  • General description: We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
  • Application: Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters
  • Other Notes: "The mer-SNS complexes form isomers in solution. This is due to the different arrangements of the SEt groups relative to the SNS ligand plane. Two of the isomers have eclipsed SEt groups (arranged on one side of the SNS plane), and the third isomer has staggered SEt groups (occupying the opposite sides of the SNS plane)."[1]
  • Legal Information: This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

SAFETY INFORMATION

Pictograms

GHS06

Signal Word

Danger

Hazard Statements

H302 + H312,H331

Precautionary Statements

P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P311

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Compare Similar Items

Show Difference

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Sigma Aldrich

746339

97%...


Quality Level:
100

Assay:
97%

form:
solid

reaction suitability:
core: rutheniumreagent type: catalyst

greener alternative product characteristics:
CatalysisLearn more about the Principles of Green Chemistry.

sustainability:
Greener Alternative Product

mp:
300-310 °C

greener alternative category:
Aligned,

SMILES string:
CCSCCN([H])CCSCC.Cl[Ru]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

InChI:
1S/C18H15P.C8H19NS2.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-10-7-5-9-6-8-11-4-2;;;/h1-15H;9H,3-8H2,1-2H3;2*1H;/q;;;;+2/p-2

Img

Sigma Aldrich

746347

97%...


Quality Level:
100

Assay:
97%

form:
solid

reaction suitability:
core: rutheniumreagent type: catalyst

greener alternative product characteristics:
CatalysisLearn more about the Principles of Green Chemistry.

sustainability:
Greener Alternative Product

mp:
275-295 °C

greener alternative category:
Aligned,

SMILES string:
Cl[Ru]Cl.[H]N(CCP(C1=CC=CC=C1)C2=CC=CC=C2)CC3=NC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6

InChI:
1S/C20H21N2P.C18H15P.2ClH.Ru/c1-3-10-19(11-4-1)23(20-12-5-2-6-13-20)16-15-21-17-18-9-7-8-14-22-18;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h1-14,21H,15-17H2;1-15H;2*1H;/q;;;;+2/p-2

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Sigma Aldrich

746363

anhydrous, free-flowing, Redi-Dri™,...


Quality Level:
100

Assay:
≥99%

form:
powder

reaction suitability:
__

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__

sustainability:
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mp:
__

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Sigma Aldrich

746363

anhydrous, free-flowing, Redi-Dri™,...


Quality Level:
100

Assay:
≥99%

form:
powder

reaction suitability:
__

greener alternative product characteristics:
__

sustainability:
__

mp:
__

greener alternative category:
__

SMILES string:
__

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__