SPhos Pd G2
Manufacturer: Sigma Aldrich
CAS Number: 1375325-64-6
Synonym(S): 2nd Generation SPhos Precatalyst, Chloro(2-dicyclohexylphosphino-2′,6′-dimethoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II), SPhos-Pd-G2
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 250 MG | 753009-250-MG | In Stock | ₹ 6,693.30 |
| IND736-1G | 753009-IND736-1G | In Stock | ₹ 10,540.00 |
| 1 G | 753009-1-G | In Stock | ₹ 16,730.00 |
| IND736-5G | 753009-IND736-5G | In Stock | ₹ 47,860.00 |
| 5 G | 753009-5-G | In Stock | ₹ 59,274.00 |
753009 - 250 MG
In Stock
Quantity
1
Base Price: ₹ 6,693.30
GST (18%): ₹ 1,204.794
Total Price: ₹ 7,898.094
form
solid
Quality Level
100
feature
generation 2
reaction suitability
core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalystreaction type: Cross Couplings
mp
218 °C (dec.)
functional group
phosphine
SMILES string
COC1=CC=CC(OC)=C1C2=C(P(C3CCCCC3)C4CCCCC4)C=CC=C2.NC5=C(C6=C([Pd]Cl)C=CC=C6)C=CC=C5
InChI
1S/C26H35O2P.C12H10N.ClH.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1-6,8-9H,13H2;1H;/q;;;+1/p-1
InChI key
NOMWEFBAPVZIIP-UHFFFAOYSA-M
Other Options
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Description
- General description: SPhos Pd G2 is a second generation (G2) precatalyst in which phenethylamine based backbone of the (G1) complex is substituted with a biphenyl-based ligand. This improvement on the previous generation allows creating the active palladium species at room temperature with weak phosphate or carbonate bases. The catalyst proves remarkably adept at achieving a variety of Suzuki-Miyaura couplings among other cross-coupling reactions.
- Application: Application in Suzuki-Miyaura coupling:Self-arylation of 1-alkyl-3-bromo-2-phenyl-2,1-borazaronaphthalenes to form 2,1-borazaronaphthols.[1]Suzuki–Miyaura coupling of [Ru(bpy)2]+ with 4-carboxyphenylboronic acid.[2]Suzuki–Miyaura coupling of β-borylated porphyrins with 2-iodoaniline.[3]
SAFETY INFORMATION
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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form: solid
Quality Level: 100
feature: generation 2
reaction suitability: core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalystreaction type: Cross Couplings
mp: 218 °C (dec.)
functional group: phosphine
SMILES string: COC1=CC=CC(OC)=C1C2=C(P(C3CCCCC3)C4CCCCC4)C=CC=C2.NC5=C(C6=C([Pd]Cl)C=CC=C6)C=CC=C5
InChI: 1S/C26H35O2P.C12H10N.ClH.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1-6,8-9H,13H2;1H;/q;;;+1/p-1
InChI key: NOMWEFBAPVZIIP-UHFFFAOYSA-M
form: solid
Quality Level: 100
feature: __
reaction suitability: __
mp: __
functional group: __
SMILES string: __
InChI: __
InChI key: __
form: liquid
Quality Level: 100
feature: __
reaction suitability: __
mp: __
functional group: __
SMILES string: Fc1c(F)c(F)c(OC(=O)C=C)c(F)c1F
InChI: 1S/C9H3F5O2/c1-2-3(15)16-9-7(13)5(11)4(10)6(12)8(9)14/h2H,1H2
InChI key: RFOWDPMCXHVGET-UHFFFAOYSA-N
