771384

[1,3-Bis(diphenylphosphino)propane]palladium(II) triflate

Manufacturer: Sigma Aldrich

CAS Number: 137846-38-9

Synonym(S): Pd(OTf)2(dippp)

Select a Size

Pack Size SKU Availability Price
1 G 771384-1-G In Stock ₹ 22,655.10

771384 - 1 G

₹ 22,655.10

In Stock

Quantity

1

Base Price: ₹ 22,655.10

GST (18%): ₹ 4,077.918

Total Price: ₹ 26,733.018

form

solid

Quality Level

100

reaction suitability

core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

mp

169-183 °C

SMILES string

[Pd++].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4

InChI

1S/C27H26P2.2CHF3O3S.Pd/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;2*2-1(3,4)8(5,6)7;/h1-12,14-21H,13,22-23H2;2*(H,5,6,7);/q;;;+2/p-2

InChI key

MIGUMLGJSGTNOK-UHFFFAOYSA-L

Other Options

Image Product Name Manufacturer Price Range
AE66241
137846-38-9 | Pd(OTf)2(dippp)
A2B Chem --

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Description

  • Application: [1,3-Bis(diphenylphosphino)propane]palladium(II) triflate can be used as a catalyst to synthesize phenanthridines by the reaction between 2-halogeno-N-Ms arylamines and benzyl halides/sulfonates via nucleophilic substitution followed by C-H functionalization and aromatization reaction.[1]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H302 + H312 + H332,H315,H319

Precautionary Statements

P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Compare Similar Items

Show Difference

Img

Sigma Aldrich

771384

--


form:
solid

Quality Level:
100

reaction suitability:
core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

mp:
169-183 °C

SMILES string:
[Pd++].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4

InChI:
1S/C27H26P2.2CHF3O3S.Pd/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;2*2-1(3,4)8(5,6)7;/h1-12,14-21H,13,22-23H2;2*(H,5,6,7);/q;;;+2/p-2

InChI key:
MIGUMLGJSGTNOK-UHFFFAOYSA-L

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Sigma Aldrich

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cell wall component...


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lyophilized powder

Quality Level:
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__

mp:
__

SMILES string:
__

InChI:
__

InChI key:
__

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Sigma Aldrich

771406

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form:
solid

Quality Level:
100

reaction suitability:
reaction type: C-C Bond Formationreagent type: catalystreaction type: C-H Activation

mp:
151-157 °C

SMILES string:
FC(F)(F)S(=O)O[Zn]OS(=O)C(F)(F)F

InChI:
__

InChI key:
__

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Sigma Aldrich

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contains <600 ppm MEHQ as inhibitor...


form:
liquid

Quality Level:
100

reaction suitability:
__

mp:
__

SMILES string:
C=COC(=O)C=C

InChI:
1S/C5H6O2/c1-3-5(6)7-4-2/h3-4H,1-2H2

InChI key:
BLCTWBJQROOONQ-UHFFFAOYSA-N