802166
2-(Pyridin-2-yl)isopropyl amine
95% (GC)
Manufacturer: Sigma Aldrich
CAS Number: 52568-28-2
Synonym(S): PIP, PIP Directing Group, Shi Auxilliary
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 500 MG | 802166-500-MG | In Stock | ₹ 7,902.25 |
802166 - 500 MG
In Stock
Quantity
1
Base Price: ₹ 7,902.25
GST (18%): ₹ 1,422.405
Total Price: ₹ 9,324.655
description
Fp: 175°F
Quality Level
100
Assay
95% (GC)
form
liquid
reaction suitability
reagent type: catalystreagent type: ligandreaction type: C-H Activation
refractive index
n/D 1.516
density
0.9800 g/mL at 25 °C
SMILES string
NC(C)(C)C1=CC=CC=N1
InChI
1S/C8H12N2/c1-8(2,9)7-5-3-4-6-10-7/h3-6H,9H2,1-2H3
InChI key
DQSQBZXDMHDHEO-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences 2-(Pyridin-2-yl)isopropyl amine 95% (GC) | 52568-28-2 | MFCD08729302 | 500MG | Sigma Aldrich Fine Chemicals Biosciences | ₹ 9,894.16 | |
 | 2-(Pyridin-2-yl)propan-2-amine | ChemScene | ₹ 1,454.52 - ₹ 31,571.64 | |
 | 52568-28-2 | [1-Methyl-1-(pyridin-2-yl)ethyl]amine | A2B Chem | ₹ 1,026.72 - ₹ 35,079.60 |
Description
- General description: 2-(Pyridin-2-yl)isopropyl amine (PIP-amine) is a tertiary amine. A bidentate directing group, useful for the functionalization of C-H bond, has been developed from PIP-amine.[1]
- Application: The Shi Auxiliary is a powerful directing group for the hydroxylation of arenes through copper-mediated C-H activation. This useful auxiliary can be removed through acid-mediated hydrolysis and has shown to be done on gram-scale.
- Other Notes: Copper-Mediated Hydroxylation of Arenes and Heteroarenes Directed by a Removable Bidentate Auxiliary
SAFETY INFORMATION
Pictograms
Signal Word
Warning
Hazard Statements
Precautionary Statements
P264 - P270 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
WGK
WGK 3
Flash Point(F)
175.0 °F
Flash Point(C)
79.44 °C
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Show Difference
description: Fp: 175°F
Quality Level: 100
Assay: 95% (GC)
form: liquid
reaction suitability: reagent type: catalystreagent type: ligandreaction type: C-H Activation
refractive index: n/D 1.516
density: 0.9800 g/mL at 25 °C
SMILES string: NC(C)(C)C1=CC=CC=N1
InChI: 1S/C8H12N2/c1-8(2,9)7-5-3-4-6-10-7/h3-6H,9H2,1-2H3
InChI key: DQSQBZXDMHDHEO-UHFFFAOYSA-N
description:
Fp: 175°F
Quality Level:
100
Assay:
95% (GC)
form:
liquid
reaction suitability:
reagent type: catalystreagent type: ligandreaction type: C-H Activation
refractive index:
n/D 1.516
density:
0.9800 g/mL at 25 °C
SMILES string:
NC(C)(C)C1=CC=CC=N1
InChI:
1S/C8H12N2/c1-8(2,9)7-5-3-4-6-10-7/h3-6H,9H2,1-2H3
InChI key:
DQSQBZXDMHDHEO-UHFFFAOYSA-N
description: __
Quality Level: 100
Assay: __
form: solid
reaction suitability: __
refractive index: __
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SMILES string: OCC(O)=O.CC(O)C(O)=O
InChI: __
InChI key: __
description:
__
Quality Level:
100
Assay:
__
form:
solid
reaction suitability:
__
refractive index:
__
density:
__
SMILES string:
OCC(O)=O.CC(O)C(O)=O
InChI:
__
InChI key:
__
description: __
Quality Level: 100
Assay: __
form: __
reaction suitability: __
refractive index: __
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SMILES string: O=C(Oc1ccccc1)c2ccccc2
InChI: 1S/C13H10O2/c14-13(11-7-3-1-4-8-11)15-12-9-5-2-6-10-12/h1-10H
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__
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__
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__
SMILES string:
O=C(Oc1ccccc1)c2ccccc2
InChI:
1S/C13H10O2/c14-13(11-7-3-1-4-8-11)15-12-9-5-2-6-10-12/h1-10H
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FCJSHPDYVMKCHI-UHFFFAOYSA-N
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SMILES string: CC1=CC(=O)Oc2cc(ccc12)N=[N+]=[N-]
InChI: 1S/C10H7N3O2/c1-6-4-10(14)15-9-5-7(12-13-11)2-3-8(6)9/h2-5H,1H3
InChI key: HEKDKVLIMUWRRZ-UHFFFAOYSA-N
description:
__
Quality Level:
100
Assay:
97%
form:
powder
reaction suitability:
__
refractive index:
__
density:
__
SMILES string:
CC1=CC(=O)Oc2cc(ccc12)N=[N+]=[N-]
InChI:
1S/C10H7N3O2/c1-6-4-10(14)15-9-5-7(12-13-11)2-3-8(6)9/h2-5H,1H3
InChI key:
HEKDKVLIMUWRRZ-UHFFFAOYSA-N