903000

[4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine] nickel (II) dichloride

Manufacturer: Sigma Aldrich

CAS Number: 1034901-50-2

Synonym(S): (4,4′-dtbbpy)NiCl2

Select a Size

Pack Size SKU Availability Price
500 MG 903000-500-MG In Stock ₹ 7,967.20

903000 - 500 MG

₹ 7,967.20

In Stock

Quantity

1

Base Price: ₹ 7,967.20

GST (18%): ₹ 1,434.096

Total Price: ₹ 9,401.296

form

powder or crystals

reaction suitability

core: nickelreaction type: Cross Couplingsreagent type: catalyst

mp

>300 °C

SMILES string

CC(C1=CC(C2=CC(C(C)(C)C)=CC=N2)=NC=C1)(C)C.Cl[Ni]Cl

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Description

  • Application: [4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine] nickel (II) dichloride can be used as a catalyst in:Decarboxylative arylation of oxo acids.[1]Acylation of ethers.[2]Cross-coupling of aryl bromides with alcohols.[3]
  • Other Notes: Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α-Oxo AcidsPhotocatalytic α-Acylation of Ethers

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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CC(C1=CC(C2=CC(C(C)(C)C)=CC=N2)=NC=C1)(C)C.Cl[Ni]Cl

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>300 °C

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powder

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core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalystreaction type: Cross Couplings

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SMILES string:
O=S(=O)([O-][Pd+2]1([C-]=2C=CC=CC2C=3C=CC=CC3[NH2]1)[P](C(C)(C)C)(C(C)(C)C)[C-]45[CH]6=[CH]7[CH]8=[CH]4[Fe+2]7869%10%11%125C=%13(C=%14C=CC=CC%14)C%12(C=%15C=CC=CC%15)=C%11(C=%16C=CC=CC%16)[C-]%10(C=%17C=CC=CC%17)C%139C=%18C=CC=CC%18)C