905917

(Ir[Me(Me)ppy]2(dtbpy))PF6

Manufacturer: Sigma Aldrich

CAS Number: 1607469-49-7

Synonym(S): 4,4′-Bis(t-butyl-2,2′-bipyridine]bis[5-methyl-2-(4-methyl-2-pyridinyl-kN)phenyl-kC]iridium hexafluorophosphate, Ir(dmppy)2(dtbbpy)PF6

Select a Size

Pack Size SKU Availability Price
100 MG 905917-100-MG In Stock ₹ 11,244.30
500 MG 905917-500-MG In Stock ₹ 46,553.40

905917 - 100 MG

₹ 11,244.30

In Stock

Quantity

1

Base Price: ₹ 11,244.30

GST (18%): ₹ 2,023.974

Total Price: ₹ 13,268.274

form

powder

reaction suitability

core: iridiumreagent type: catalystreaction type: Photocatalysis

photocatalyst activation

465 nm

SMILES string

F[P-](F)(F)(F)(F)F.CC1=CC([Ir+]([N]2=C3C=C(C)C=C2)(C4=C5C=CC(C)=C4)([N]6=C7C=C(C(C)(C)C)C=C6)([N]8=C7C=C(C(C)(C)C)C=C8)[N]9=C5C=C(C)C=C9)=C3C=C1

Related Products

Img

Sigma Aldrich

908703

≥95%...

Img

Sigma Aldrich

908568

≥95%...

Img

Sigma Aldrich

901409

--

Img

Sigma Aldrich

904945

≥95%...

Img

Sigma Aldrich

904953

≥95%...

Img

Sigma Aldrich

900539

--

Img

Sigma Aldrich

900538

--

Img

Sigma Aldrich

904694

≥95%...

Description

  • Application: (Ir[Me(Me)ppy]2(dtbpy))PF6 or Ir(dmppy)2(dtbbpy)PF6 is an iridium photoredox catalyst that facilitates a variety of transformations using visible light, including the α- and β-alkylation of aldehydes.[1][2]Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
  • Other Notes: Direct β-Alkylation of Aldehydes via Photoredox OrganocatalysisDirect, enantioselective α-alkylation of aldehydes using simple olefins

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Compare Similar Items

Show Difference

Img

Sigma Aldrich

905917

--


form:
powder

reaction suitability:
core: iridiumreagent type: catalystreaction type: Photocatalysis

photocatalyst activation:
465 nm

SMILES string:
F[P-](F)(F)(F)(F)F.CC1=CC([Ir+]([N]2=C3C=C(C)C=C2)(C4=C5C=CC(C)=C4)([N]6=C7C=C(C(C)(C)C)C=C6)([N]8=C7C=C(C(C)(C)C)C=C8)[N]9=C5C=C(C)C=C9)=C3C=C1

Img

Sigma Aldrich

905925

≥95%...


form:
powder or crystals

reaction suitability:
core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

photocatalyst activation:
__

SMILES string:
ClC(C=C1)=NC2=C1C=CC3=CC=C[N]([Pd]45[N]6=C(C7=CC=CC=[N]75)C=CC=C6C8=CC=CC=[N]84)=C32

Img

Supelco

90593

analytical standard...


form:
__

reaction suitability:
__

photocatalyst activation:
__

SMILES string:
COc1cc(\C=C\C(=O)CC(=O)\C=C\c2ccc(O)cc2)ccc1O

Img

Supelco

90594

analytical standard...


form:
__

reaction suitability:
__

photocatalyst activation:
__

SMILES string:
Oc1ccc(cc1)\C=C\C(=O)CC(=O)\C=C\c2ccc(O)cc2