911828
PhPAd-DalPhos Ni(o-tolyl)Cl
≥95%
Manufacturer: Sigma Aldrich
CAS Number: 2290490-29-6
Synonym(S): (SP-4-3)-Chloro[8-[2-(diphenylphosphino-κP)phenyl]-1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane-κP8](2-methylphenyl)nickel
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 250 MG | 911828-250-MG | In Stock | ₹ 59,093.68 |
911828 - 250 MG
In Stock
Quantity
1
Base Price: ₹ 59,093.68
GST (18%): ₹ 10,636.862
Total Price: ₹ 69,730.542
Assay
≥95%
form
powder
reaction suitability
reagent type: catalystreaction type: Cross Couplings
mp
235-248 °C
SMILES string
Cl[Ni]1(P(C(C2)(O3)C)(C4=CC=CC=C4P(C5=CC=CC=C5)1C6=CC=CC=C6)[C@@](C[C@]3(OC27C)C)(O7)C)C(C=CC=C8)=C8C
Related Products
Description
- Application: PhPAd-DalPhos Ni(o-tolyl)Cl is an air stable precatalyst developed in the Stradiotto lab used for coupling of bulky primary amines with arenes.
- Other Notes: Technology Spotlight: DalPhos ligandsPhPAd-DalPhos: Ligand-Enabled, Nickel-Catalyzed Cross-Coupling of (Hetero)aryl Electrophiles with Bulky Primary Alkylamines
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Muta. 2 - Repr. 2 - Resp. Sens. 1 - STOT RE 1
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Compare Similar Items
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Assay: ≥95%
form: powder
reaction suitability: reagent type: catalystreaction type: Cross Couplings
mp: 235-248 °C
SMILES string: Cl[Ni]1(P(C(C2)(O3)C)(C4=CC=CC=C4P(C5=CC=CC=C5)1C6=CC=CC=C6)[C@@](C[C@]3(OC27C)C)(O7)C)C(C=CC=C8)=C8C
Assay:
≥95%
form:
powder
reaction suitability:
reagent type: catalystreaction type: Cross Couplings
mp:
235-248 °C
SMILES string:
Cl[Ni]1(P(C(C2)(O3)C)(C4=CC=CC=C4P(C5=CC=CC=C5)1C6=CC=CC=C6)[C@@](C[C@]3(OC27C)C)(O7)C)C(C=CC=C8)=C8C
Assay: __
form: powder
reaction suitability: reagent type: catalystreaction type: Cross Couplings
mp: 141-143 °C
SMILES string: CC(C1CCC2=C1C=CC=C2)(C)C.C[Pd](Cl)P(C(C)(C)C)(C(C)(C)C)C(C)(C)C.CC
Assay:
__
form:
powder
reaction suitability:
reagent type: catalystreaction type: Cross Couplings
mp:
141-143 °C
SMILES string:
CC(C1CCC2=C1C=CC=C2)(C)C.C[Pd](Cl)P(C(C)(C)C)(C(C)(C)C)C(C)(C)C.CC
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