923478
CyMPhos
Manufacturer: Sigma Aldrich
Synonym(S): 1-Diadamantylphosphino-1′-dicyclohexylphosphinoferrocene
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 923478-100-MG | In Stock | ₹ 8,162.05 |
| 500 MG | 923478-500-MG | In Stock | ₹ 24,486.15 |
923478 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 8,162.05
GST (18%): ₹ 1,469.169
Total Price: ₹ 9,631.219
reaction suitability
reagent type: catalystreaction type: Cross Couplingsreagent type: ligand
Quality Level
100
functional group
phosphine
SMILES string
c1(P(C2CCCCC2)C3CCCCC3)cccc1.c4(P([C@@]56C[C@@H](C[C@H]7C6)C[C@@H](C7)C5)[C@@]89C[C@@H](C[C@H]%10C9)C[C@@H](C%10)C8)cccc4.[Fe]
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Description
- Application: CyMPhos is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing CyMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).Learn more about MPhos ligands and catalysts
- Other Notes: Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp2–Csp3 Couplings
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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reaction suitability: reagent type: catalystreaction type: Cross Couplingsreagent type: ligand
Quality Level: 100
functional group: phosphine
SMILES string: c1(P(C2CCCCC2)C3CCCCC3)cccc1.c4(P([C@@]56C[C@@H](C[C@H]7C6)C[C@@H](C7)C5)[C@@]89C[C@@H](C[C@H]%10C9)C[C@@H](C%10)C8)cccc4.[Fe]
reaction suitability:
reagent type: catalystreaction type: Cross Couplingsreagent type: ligand
Quality Level:
100
functional group:
phosphine
SMILES string:
c1(P(C2CCCCC2)C3CCCCC3)cccc1.c4(P([C@@]56C[C@@H](C[C@H]7C6)C[C@@H](C7)C5)[C@@]89C[C@@H](C[C@H]%10C9)C[C@@H](C%10)C8)cccc4.[Fe]
reaction suitability: reagent type: catalystreaction type: Cross Couplings
Quality Level: 100
functional group: __
SMILES string: __
reaction suitability:
reagent type: catalystreaction type: Cross Couplings
Quality Level:
100
functional group:
__
SMILES string:
__
reaction suitability: reagent type: catalystreaction type: Cross Couplingsreagent type: ligand
Quality Level: 100
functional group: phosphine
SMILES string: __
reaction suitability:
reagent type: catalystreaction type: Cross Couplingsreagent type: ligand
Quality Level:
100
functional group:
phosphine
SMILES string:
__
reaction suitability: reagent type: catalystreaction type: Cross Couplings
Quality Level: 100
functional group: __
SMILES string: Cl[Pd](Cl)([P](c1cccc1)(C23C[C@H]4C[C@H](C[C@H](C4)C3)C2)C56C[C@H]7C[C@H](C[C@H](C7)C6)C5)[P](c8cccc8)(C(C)C)C(C)C.[Fe]
reaction suitability:
reagent type: catalystreaction type: Cross Couplings
Quality Level:
100
functional group:
__
SMILES string:
Cl[Pd](Cl)([P](c1cccc1)(C23C[C@H]4C[C@H](C[C@H](C4)C3)C2)C56C[C@H]7C[C@H](C[C@H](C7)C6)C5)[P](c8cccc8)(C(C)C)C(C)C.[Fe]