171565
Phenylmagnesium bromide solution
3.0 M in diethyl ether
Manufacturer: Sigma Aldrich
CAS Number: 100-58-3
Synonym(S): Bromomagnesiobenzene, Bromophenylmagnesium
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 50 ML | 171565-50-ML | In Stock | ₹ 4,990.33 |
| 100 ML | 171565-100-ML | In Stock | ₹ 7,030.00 |
| 4 X 25 ML | 171565-4-X-25-ML | In Stock | ₹ 9,471.88 |
| 800 ML | 171565-800-ML | In Stock | ₹ 18,229.30 |
171565 - 50 ML
In Stock
Quantity
1
Base Price: ₹ 4,990.33
GST (18%): ₹ 898.259
Total Price: ₹ 5,888.589
Quality Level
200
reaction suitability
reaction type: Grignard Reaction
concentration
3.0 M in diethyl ether
density
1.134 g/mL at 25 °C
SMILES string
Br[Mg]c1ccccc1
InChI
1S/C6H5.BrH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
InChI key
ANRQGKOBLBYXFM-UHFFFAOYSA-M
Other Options
Related Products
Description
- General description: Phenylmagnesium bromide solution contains 3M phenylmagnesium bromide in diethyl ether. It can act as a strong acid and Lewis acid. It can undergo addition reaction with many unsaturated functional groups. The phenyl group can displace halide from other organic compounds.[1] Phenylmagnesium bromide is a Grignard reagent. Reaction of β-cyclohexanedione (dihydroresorcinol) with phenylmagnesium bromide has been investigated.[2]
- Application: Phenylmagnesium bromide was used for the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s.[3] It was also used for the monoalkylation of aliphatic primary amine to generate secondary amines by the Grignard reaction of 1-[(alkylamino) methyl] benzotriazoles.[4] It may be used for synthesis of the following: 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol[5] 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol[5] (3-(2-Dithiobenzoatepropionyl)propyl)dimethylmethoxysilane, reversible addition-fragmentation chain transfer polymerization (RAFT)-silane agent[6] series of o-substituted benzophenones[7]
- Packaging: View returnable container options.
- Other Notes: Storage below 25°C may cause formation of crystalline magnesium salts. Moving container to a warm location and occasional gentle swirling should redissolve the solid
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Supplementary Hazards
EUH014,EUH019
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 200
reaction suitability: reaction type: Grignard Reaction
concentration: 3.0 M in diethyl ether
density: 1.134 g/mL at 25 °C
SMILES string: Br[Mg]c1ccccc1
InChI: 1S/C6H5.BrH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
InChI key: ANRQGKOBLBYXFM-UHFFFAOYSA-M
Quality Level:
200
reaction suitability:
reaction type: Grignard Reaction
concentration:
3.0 M in diethyl ether
density:
1.134 g/mL at 25 °C
SMILES string:
Br[Mg]c1ccccc1
InChI:
1S/C6H5.BrH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
InChI key:
ANRQGKOBLBYXFM-UHFFFAOYSA-M
Quality Level: 100
reaction suitability: __
concentration: __
density: 1.001 g/mL at 25 °C (lit.)
SMILES string: N#CCCc1ccccc1
InChI: 1S/C9H9N/c10-8-4-7-9-5-2-1-3-6-9/h1-3,5-6H,4,7H2
InChI key: ACRWYXSKEHUQDB-UHFFFAOYSA-N
Quality Level:
100
reaction suitability:
__
concentration:
__
density:
1.001 g/mL at 25 °C (lit.)
SMILES string:
N#CCCc1ccccc1
InChI:
1S/C9H9N/c10-8-4-7-9-5-2-1-3-6-9/h1-3,5-6H,4,7H2
InChI key:
ACRWYXSKEHUQDB-UHFFFAOYSA-N
Quality Level: __
reaction suitability: __
concentration: __
density: __
SMILES string: __
InChI: 1S/C22H32O2/c1-17(9-7-10-18(2)14-16-24-20(4)23)12-13-21-19(3)11-8-15-22(21,5)6/h7,9-10,12-14H,8,11,15-16H2,1-6H3/b10-7+,13-12+,17-9+,18-14+
InChI key: QGNJRVVDBSJHIZ-QHLGVNSISA-N
Quality Level:
__
reaction suitability:
__
concentration:
__
density:
__
SMILES string:
__
InChI:
1S/C22H32O2/c1-17(9-7-10-18(2)14-16-24-20(4)23)12-13-21-19(3)11-8-15-22(21,5)6/h7,9-10,12-14H,8,11,15-16H2,1-6H3/b10-7+,13-12+,17-9+,18-14+
InChI key:
QGNJRVVDBSJHIZ-QHLGVNSISA-N
Quality Level: 100
reaction suitability: reaction type: solution phase peptide synthesis
concentration: __
density: __
SMILES string: O.NC(C(O)c1ccccc1)C(O)=O
InChI: 1S/C9H11NO3.H2O/c10-7(9(12)13)8(11)6-4-2-1-3-5-6;/h1-5,7-8,11H,10H2,(H,12,13);1H2
InChI key: DUGXBGWTWDCGNP-UHFFFAOYSA-N
Quality Level:
100
reaction suitability:
reaction type: solution phase peptide synthesis
concentration:
__
density:
__
SMILES string:
O.NC(C(O)c1ccccc1)C(O)=O
InChI:
1S/C9H11NO3.H2O/c10-7(9(12)13)8(11)6-4-2-1-3-5-6;/h1-5,7-8,11H,10H2,(H,12,13);1H2
InChI key:
DUGXBGWTWDCGNP-UHFFFAOYSA-N