225584
Vinylmagnesium bromide solution
1.0 M in THF
Manufacturer: Sigma Aldrich
CAS Number: 1826-67-1
Synonym(S): Bromoethenylmagnesium, Bromovinylmagnesium
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 ML | 225584-100-ML | In Stock | ₹ 7,588.33 |
| 4 X 25 ML | 225584-4-X-25-ML | In Stock | ₹ 8,605.88 |
| 4 X 100 ML | 225584-4-X-100-ML | In Stock | ₹ 22,277.85 |
| 800 ML | 225584-800-ML | In Stock | ₹ 26,564.55 |
| 18 L | 225584-18-L | In Stock | ₹ 2,51,367.33 |
225584 - 100 ML
In Stock
Quantity
1
Base Price: ₹ 7,588.33
GST (18%): ₹ 1,365.899
Total Price: ₹ 8,954.229
Quality Level
100
reaction suitability
reaction type: Grignard Reaction
concentration
1.0 M in THF
density
0.981 g/mL at 25 °C
SMILES string
Br[Mg]C=C
InChI
1S/C2H3.BrH.Mg/c1-2;;/h1H,2H2;1H;/q;;+1/p-1
InChI key
XHHHAXOHMKAOSL-UHFFFAOYSA-M
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences Vinylmagnesium bromide solution | 1826-67-1 | MFCD00000042 | 4 x 100mL | Sigma Aldrich Fine Chemicals Biosciences | ₹ 26,621.99 | |
 | Sigma Aldrich Fine Chemicals Biosciences Vinylmagnesium bromide solution 1.0 M in THF | 1826-67-1 | MFCD00000042 | 1.8L | Sigma Aldrich Fine Chemicals Biosciences | ₹ 68,451.42 | |
 | Sigma Aldrich Fine Chemicals Biosciences Vinylmagnesium Bromide Solution | 1826-67-1 | MFCD00000042 | 200ml | Sigma Aldrich Fine Chemicals Biosciences | ₹ 23,163.66 |
Related Products
Description
- Application: Vinylmagnesium bromide solution (1 M in THF) may be used in the synthesis of 2-vinylchroman-4-ones by the conjugate addition with chromones in the presence of a Lewis acid.[1]It may also be used in the following transformations: (S)-3-(benzyloxy)-4-oxo-butanoic acid methyl ester to methyl (3S,4S)-4-hydroxy-3-(phenylmethoxy)hex-5-enoate.[2](R)-1-Azido-5,6-epoxyhexane to (S)-1-(4-azidobutyl)-2-propen-1-ol.[3]2,3-O-Isopropylidene-D-ribose to 1-[(4R,5S)-5-((1S)-1-hydroxyallyl)-2,2-dimethyl[1,3]dioxolan-4-yl]ethane-1,2-diol.[4](4S,5S)-2,2-Dimethyl-5-vinyl[1,3]dioxolane-4-carbaldehyde to (1R,4R,5S)- and (1S,4R,5S)-1-(2,2-dimethyl-5-vinyl[1,3]dioxolan-4-yl)prop-2-en-1-ol.[4]Ethyl levulinate to ?-methyl-?-vinylbutyrolactone.[5]
- Packaging: View returnable container options.
- Other Notes: Storage below 25°C may cause crystallization. Warm gently to redissolve.
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3 - Water-react 1
Target Organs
Respiratory system
Supplementary Hazards
EUH019
WGK
WGK 1
Flash Point(F)
1.4 °F
Flash Point(C)
-17.0 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 100
reaction suitability: reaction type: Grignard Reaction
concentration: 1.0 M in THF
density: 0.981 g/mL at 25 °C
SMILES string: Br[Mg]C=C
InChI: 1S/C2H3.BrH.Mg/c1-2;;/h1H,2H2;1H;/q;;+1/p-1
InChI key: XHHHAXOHMKAOSL-UHFFFAOYSA-M
Quality Level:
100
reaction suitability:
reaction type: Grignard Reaction
concentration:
1.0 M in THF
density:
0.981 g/mL at 25 °C
SMILES string:
Br[Mg]C=C
InChI:
1S/C2H3.BrH.Mg/c1-2;;/h1H,2H2;1H;/q;;+1/p-1
InChI key:
XHHHAXOHMKAOSL-UHFFFAOYSA-M
Quality Level: 200
reaction suitability: __
concentration: __
density: 0.976 g/mL at 20 °C (lit.)
SMILES string: NCCN(CCN)CCN
InChI: 1S/C6H18N4/c7-1-4-10(5-2-8)6-3-9/h1-9H2
InChI key: __
Quality Level:
200
reaction suitability:
__
concentration:
__
density:
0.976 g/mL at 20 °C (lit.)
SMILES string:
NCCN(CCN)CCN
InChI:
1S/C6H18N4/c7-1-4-10(5-2-8)6-3-9/h1-9H2
InChI key:
__
Quality Level: 200
reaction suitability: __
concentration: __
density: 1.228 g/mL at 25 °C (lit.)
SMILES string: C[Si](C)(C)OS(=O)(=O)C(F)(F)F
InChI: 1S/C4H9F3O3SSi/c1-12(2,3)10-11(8,9)4(5,6)7/h1-3H3
InChI key: FTVLMFQEYACZNP-UHFFFAOYSA-N
Quality Level:
200
reaction suitability:
__
concentration:
__
density:
1.228 g/mL at 25 °C (lit.)
SMILES string:
C[Si](C)(C)OS(=O)(=O)C(F)(F)F
InChI:
1S/C4H9F3O3SSi/c1-12(2,3)10-11(8,9)4(5,6)7/h1-3H3
InChI key:
FTVLMFQEYACZNP-UHFFFAOYSA-N
Quality Level: 200
reaction suitability: core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst
concentration: __
density: __
SMILES string: CC#N.CC#N.Cl[Pd]Cl
InChI: 1S/2C2H3N.2ClH.Pd/c2*1-2-3;;;/h2*1H3;2*1H;/q;;;;+2/p-2
InChI key: RBYGDVHOECIAFC-UHFFFAOYSA-L
Quality Level:
200
reaction suitability:
core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst
concentration:
__
density:
__
SMILES string:
CC#N.CC#N.Cl[Pd]Cl
InChI:
1S/2C2H3N.2ClH.Pd/c2*1-2-3;;;/h2*1H3;2*1H;/q;;;;+2/p-2
InChI key:
RBYGDVHOECIAFC-UHFFFAOYSA-L