274259
Methyl P,P-bis(2,2,2-trifluoroethyl)phosphonoacetate
95%
Manufacturer: Sigma Aldrich
CAS Number: 88738-78-7
Synonym(S): Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 5 G | 274259-5-G | In Stock | ₹ 16,360.00 |
274259 - 5 G
In Stock
Quantity
1
Base Price: ₹ 16,360.00
GST (18%): ₹ 2,944.80
Total Price: ₹ 19,304.80
Assay
95%
form
liquid
reaction suitability
reaction type: C-C Bond Formation
refractive index
n20/D 1.370 (lit.)
density
1.504 g/mL at 25 °C (lit.)
SMILES string
COC(=O)CP(=O)(OCC(F)(F)F)OCC(F)(F)F
InChI
1S/C7H9F6O5P/c1-16-5(14)2-19(15,17-3-6(8,9)10)18-4-7(11,12)13/h2-4H2,1H3
InChI key
PVSJXEDBEXYLML-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | eMolecules Ambeed / Methyl 2-(bis(222-trifluoroethoxy)phosphoryl)acetate / 1g / 527374680 / A293318 / / 88738-78-7 / MFCD00009901 / 318.108 / C7H9F6O5P | eMolecules | ₹ 3,880.40 | |
 | BIS(2,2,2-TRIFLUOROETHYL) (METHOXYCARBONYLMETHYL)PHOSPHONATE | Aaron Chemicals LLC | ₹ 445.00 - ₹ 1,10,983.00 | |
 | Methyl 2-(bis(2,2,2-trifluoroethoxy)phosphoryl)acetate | ChemScene | ₹ 1,068.00 - ₹ 45,835.00 | |
 | 88738-78-7 | Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate | A2B Chem | ₹ 445.00 - ₹ 24,030.00 |
Related Products
Description
- Application: Methyl P,P-bis(2,2,2-trifluoroethyl)phosphonoacetate can be used:In one of the key synthetic steps for the preparation of trans-hydrindanes and (R)-(+)-umbelactone.[1][2]To prepare a cis-olefinic ester derivative by Still–Gennari olefination of an aldehyde derivative using 18-crown ether and potassium bis(trimethylsilyl)amide (KHMDS).[3]In the synthesis of (−)-(6S,2′S)-epi cryptocaryalactone.[4]
SAFETY INFORMATION
Pictograms
Signal Word
Warning
Hazard Statements
Precautionary Statements
P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Assay: 95%
form: liquid
reaction suitability: reaction type: C-C Bond Formation
refractive index: n20/D 1.370 (lit.)
density: 1.504 g/mL at 25 °C (lit.)
SMILES string: COC(=O)CP(=O)(OCC(F)(F)F)OCC(F)(F)F
InChI: 1S/C7H9F6O5P/c1-16-5(14)2-19(15,17-3-6(8,9)10)18-4-7(11,12)13/h2-4H2,1H3
InChI key: PVSJXEDBEXYLML-UHFFFAOYSA-N
Assay:
95%
form:
liquid
reaction suitability:
reaction type: C-C Bond Formation
refractive index:
n20/D 1.370 (lit.)
density:
1.504 g/mL at 25 °C (lit.)
SMILES string:
COC(=O)CP(=O)(OCC(F)(F)F)OCC(F)(F)F
InChI:
1S/C7H9F6O5P/c1-16-5(14)2-19(15,17-3-6(8,9)10)18-4-7(11,12)13/h2-4H2,1H3
InChI key:
PVSJXEDBEXYLML-UHFFFAOYSA-N
Assay: __
form: __
reaction suitability: __
refractive index: __
density: __
SMILES string: __
InChI: __
InChI key: __
Assay:
__
form:
__
reaction suitability:
__
refractive index:
__
density:
__
SMILES string:
__
InChI:
__
InChI key:
__
Assay: __
form: __
reaction suitability: __
refractive index: __
density: __
SMILES string: __
InChI: __
InChI key: __
Assay:
__
form:
__
reaction suitability:
__
refractive index:
__
density:
__
SMILES string:
__
InChI:
__
InChI key:
__
Assay: __
form: viscous liquid
reaction suitability: __
refractive index: n20/D 1.468 (lit.)
density: 1.095 g/mL at 25 °C (lit.)
SMILES string: CCCCCCCCCCCC(=O)OCCOCC(C1C(C(CO1)OCCO)OCCO)OCCO
InChI: 1S/C26H50O10/c1-2-3-4-5-6-7-8-9-10-11-24(30)34-19-18-31-20-22(32-15-12-27)26-25(35-17-14-29)23(21-36-26)33-16-13-28/h22-23,25-29H,2-21H2,1H3
InChI key: HMFKFHLTUCJZJO-UHFFFAOYSA-N
Assay:
__
form:
viscous liquid
reaction suitability:
__
refractive index:
n20/D 1.468 (lit.)
density:
1.095 g/mL at 25 °C (lit.)
SMILES string:
CCCCCCCCCCCC(=O)OCCOCC(C1C(C(CO1)OCCO)OCCO)OCCO
InChI:
1S/C26H50O10/c1-2-3-4-5-6-7-8-9-10-11-24(30)34-19-18-31-20-22(32-15-12-27)26-25(35-17-14-29)23(21-36-26)33-16-13-28/h22-23,25-29H,2-21H2,1H3
InChI key:
HMFKFHLTUCJZJO-UHFFFAOYSA-N