298352

(1S)-(−)-2,10-Camphorsultam

98%

Manufacturer: Sigma Aldrich

CAS Number: 94594-90-8

Synonym(S): (−)-10,2-Camphorsultam, (−)-exo-10,2-Bornanesultam, (1S,5R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]decane 3,3-dioxide, [3aS-(3aα,6α,7aβ)]-hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole-2,2-dioxide

Select a Size

Pack Size SKU Availability Price
5 G 298352-5-G In Stock ₹ 11,669.35

298352 - 5 G

₹ 11,669.35

In Stock

Quantity

1

Base Price: ₹ 11,669.35

GST (18%): ₹ 2,100.483

Total Price: ₹ 13,769.833

Quality Level

200

Assay

98%

form

solid

optical activity

[α]19/D −32°, c = 5 in chloroform

mp

181-183 °C (lit.)

SMILES string

[H][C@@]12CC[C@]3(CS(=O)(=O)N[C@@H]3C1)C2(C)C

InChI

1S/C10H17NO2S/c1-9(2)7-3-4-10(9)6-14(12,13)11-8(10)5-7/h7-8,11H,3-6H2,1-2H3/t7-,8-,10-/m1/s1

InChI key

DPJYJNYYDJOJNO-NQMVMOMDSA-N

Other Options

Image Product Name Manufacturer Price Range
CS-W014890
(3aS,6S,7aS)-8,8-Dimethylhexahydro-1H-3a,6-methanobenzo[c]isothiazole 2,2-dioxide
ChemScene ₹ 1,026.72 - ₹ 45,689.04

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Description

  • General description: (1S,2R,4R)-(−)-2,10-Camphorsultam may be employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids.[1]
  • Application: (1S)-(−)-2,10-Camphorsultam may be used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine.[2] It may be used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones.[3]

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

298352

98%...


Quality Level:
200

Assay:
98%

form:
solid

optical activity:
[α]19/D −32°, c = 5 in chloroform

mp:
181-183 °C (lit.)

SMILES string:
[H][C@@]12CC[C@]3(CS(=O)(=O)N[C@@H]3C1)C2(C)C

InChI:
1S/C10H17NO2S/c1-9(2)7-3-4-10(9)6-14(12,13)11-8(10)5-7/h7-8,11H,3-6H2,1-2H3/t7-,8-,10-/m1/s1

InChI key:
DPJYJNYYDJOJNO-NQMVMOMDSA-N

Img

Sigma Aldrich

298360

optical purity ee: 99% (GLC)...


Quality Level:
200

Assay:
__

form:
solid

optical activity:
[α]22/D −14°, c = 10 in H2O

mp:
149-155 °C (lit.)

SMILES string:
[Na+].C[C@@H](O)CC([O-])=O

InChI:
1S/C4H8O3.Na/c1-3(5)2-4(6)7;/h3,5H,2H2,1H3,(H,6,7);/q;+1/p-1/t3-;/m1./s1

InChI key:
NBPUSGBJDWCHKC-AENDTGMFSA-M

Img

Sigma Aldrich

298417

98%...


Quality Level:
100

Assay:
98%

form:
__

optical activity:
[α]20/D −4°, c = 9 in ethanol

mp:
__

SMILES string:
CC(C)C[C@@H](N)CO

InChI:
1S/C6H15NO/c1-5(2)3-6(7)4-8/h5-6,8H,3-4,7H2,1-2H3/t6-/m1/s1

InChI key:
__

Img

Sigma Aldrich

298433

in excess methyl sulfide...


Quality Level:
100

Assay:
__

form:
__

optical activity:
__

mp:
__

SMILES string:
C[S+](C)[BH-](Cl)Cl

InChI:
1S/C2H7BCl2S/c1-6(2)3(4)5/h3H,1-2H3

InChI key:
UMDZKXAEAKAIPA-UHFFFAOYSA-N