309567

(Methoxymethyl)triphenylphosphonium chloride

97%

Manufacturer: Sigma Aldrich

CAS Number: 4009-98-7

Synonym(S): Triphenyl(methoxymethyl)phosphonium chloride

Select a Size

Pack Size SKU Availability Price
25 G 309567-25-G In Stock ₹ 2,717.08
100 G 309567-100-G In Stock ₹ 8,378.55

309567 - 25 G

₹ 2,717.08

In Stock

Quantity

1

Base Price: ₹ 2,717.08

GST (18%): ₹ 489.074

Total Price: ₹ 3,206.154

Quality Level

100

Assay

97%

form

solid

reaction suitability

reaction type: C-C Bond Formation

mp

185-195 °C (dec.) (lit.)

SMILES string

[Cl-].COC[P+](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C20H20OP.ClH/c1-21-17-22(18-11-5-2-6-12-18,19-13-7-3-8-14-19)20-15-9-4-10-16-20;/h2-16H,17H2,1H3;1H/q+1;/p-1

InChI key

SJFNDMHZXCUXSA-UHFFFAOYSA-M

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Description

  • Application: (Methoxymethyl)triphenylphosphonium chloride is a Wittig reagent that reacts with aldehydes and ketones to give substituted alkenes. This Wittig reaction finds application as the key step in the synthesis of:Antimalarial drug, (+)-artemisinin.[1]Substituted quinolines.[2]Akuammiline alkaloid picrinine.[3]7H-pyrrolo[2,3-d]pyrimidine derivatives for signal transducers and activators of transcription 6 (STAT6) inhibitors.[4]

SAFETY INFORMATION

Pictograms

GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302,H315,H319,H411

Precautionary Statements

P264 - P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2

WGK

WGK 2

Flash Point(F)

>482.0 °F

Flash Point(C)

> 250 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

309567

97%...


Quality Level:
100

Assay:
97%

form:
solid

reaction suitability:
reaction type: C-C Bond Formation

mp:
185-195 °C (dec.) (lit.)

SMILES string:
[Cl-].COC[P+](c1ccccc1)(c2ccccc2)c3ccccc3

InChI:
1S/C20H20OP.ClH/c1-21-17-22(18-11-5-2-6-12-18,19-13-7-3-8-14-19)20-15-9-4-10-16-20;/h2-16H,17H2,1H3;1H/q+1;/p-1

InChI key:
SJFNDMHZXCUXSA-UHFFFAOYSA-M

Img

Supelco

30958

certified reference material, Trace...


Quality Level:
300

Assay:
__

form:
__

reaction suitability:
__

mp:
163-165 °C (lit.)

SMILES string:
__

InChI:
__

InChI key:
__

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Sigma Aldrich

309583

95%...


Quality Level:
100

Assay:
95%

form:
viscous liquid

reaction suitability:
__

mp:
__

SMILES string:
Cc1ccc(cc1)S(=O)(=O)OCCOCCOCCOCCOCCOS(=O)(=O)c2ccc(C)cc2

InChI:
1S/C24H34O10S2/c1-21-3-7-23(8-4-21)35(25,26)33-19-17-31-15-13-29-11-12-30-14-16-32-18-20-34-36(27,28)24-9-5-22(2)6-10-24/h3-10H,11-20H2,1-2H3

InChI key:
BUHGDYPBQWWWQS-UHFFFAOYSA-N

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Sigma Aldrich

309591

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Quality Level:
200

Assay:
99%

form:
__

reaction suitability:
__

mp:
__

SMILES string:
[Na+].[H]O[H].CC(C)(C)C([O-])=O

InChI:
1S/C5H10O2.Na.H2O/c1-5(2,3)4(6)7;;/h1-3H3,(H,6,7);;1H2/q;+1;/p-1

InChI key:
OXKVPNMBQUHJHF-UHFFFAOYSA-M