323136

Trimethylboroxine

99%

Manufacturer: Sigma Aldrich

CAS Number: 823-96-1

Synonym(S): 2,4,6-Trimethyl-1,3,5,2,4,6-trioxatriborinane, 2,4,6-Trimethylboroxine, Methaneboronic anhydride, Trimethyl-1,3,5,2,4,6-trioxatriborinane

Select a Size

Pack Size SKU Availability Price
1 G 323136-1-G In Stock ₹ 5,141.88
5 G 323136-5-G In Stock ₹ 13,044.13
25 G 323136-25-G In Stock ₹ 49,535.20
250 G 323136-250-G In Stock ₹ 1,97,015.00

323136 - 1 G

₹ 5,141.88

In Stock

Quantity

1

Base Price: ₹ 5,141.88

GST (18%): ₹ 925.538

Total Price: ₹ 6,067.418

Quality Level

100

Assay

99%

form

liquid

refractive index

n20/D 1.362 (lit.)

bp

78-80 °C (lit.)

mp

−38 °C (lit.)

density

0.898 g/mL at 25 °C (lit.)

SMILES string

Cb1ob(C)ob(C)o1

InChI

1S/C3H9B3O3/c1-4-7-5(2)9-6(3)8-4/h1-3H3

InChI key

GBBSAMQTQCPOBF-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-180-4010
Sigma Aldrich Fine Chemicals Biosciences Trimethylboroxine | 823-96-1 | MFCD00013354 | 25g
Sigma Aldrich Fine Chemicals Biosciences ₹ 36,998.71
AR00375R
Trimethylboroxine
Aaron Chemicals LLC --
AB48147
823-96-1 | Trimethylboroxine 50% w/w soln. in THF
A2B Chem --

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Description

  • Application: Trimethylboroxine (TMB) is a cyclic anhydride of methyl-boronic acid. It can be been used:As a derivatizing agent for gas chromatographic/mass spectrometric analysis.[1]In the preparation of methylaluminoxane (MAO) which is used in the polymerization of olefins.[2]As an electrolyte additive to enhance the interface stability of electrode/electrolyte.[3]In methylation of aryl halides by palladium-catalyzed Suzuki-Miyaura coupling reaction.[4]In the preparation of CBS (Corey, Bakshi and Shibata) catalysts for asymmetric reductions of ketones to alcohols.[5]

SAFETY INFORMATION

Pictograms

GHS02,GHS05

Signal Word

Danger

Hazard Statements

H225,H314

Precautionary Statements

P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Flam. Liq. 2 - Skin Corr. 1B

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

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Sigma Aldrich

323136

99%...


Quality Level:
100

Assay:
99%

form:
liquid

refractive index:
n20/D 1.362 (lit.)

bp:
78-80 °C (lit.)

mp:
−38 °C (lit.)

density:
0.898 g/mL at 25 °C (lit.)

SMILES string:
Cb1ob(C)ob(C)o1

InChI:
1S/C3H9B3O3/c1-4-7-5(2)9-6(3)8-4/h1-3H3

InChI key:
GBBSAMQTQCPOBF-UHFFFAOYSA-N

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Sigma Aldrich

323144

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form:
__

refractive index:
__

bp:
__

mp:
70-71 °C (lit.)

density:
__

SMILES string:
C[C@H](O)c1ccc2ccccc2c1

InChI:
1S/C12H12O/c1-9(13)11-7-6-10-4-2-3-5-12(10)8-11/h2-9,13H,1H3/t9-/m0/s1

InChI key:
AXRKCRWZRKETCK-VIFPVBQESA-N

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Sigma Aldrich

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form:
liquid

refractive index:
__

bp:
__

mp:
__

density:
1.517 g/mL at 25 °C

SMILES string:
BrC(=O)C(Br)=O

InChI:
1S/C2Br2O2/c3-1(5)2(4)6

InChI key:
JAZLVNXWYDFQFE-UHFFFAOYSA-N

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Sigma Aldrich

323276

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100

Assay:
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form:
solid

refractive index:
__

bp:
__

mp:
65-70 °C (lit.)

density:
__

SMILES string:
ONC(=O)OCc1ccccc1

InChI:
1S/C8H9NO3/c10-8(9-11)12-6-7-4-2-1-3-5-7/h1-5,11H,6H2,(H,9,10)

InChI key:
PQBSPTAPCMSZAA-UHFFFAOYSA-N