335452
Lithium (trimethylsilyl)acetylide solution
0.5 M in THF
Manufacturer: Sigma Aldrich
CAS Number: 54655-07-1
Synonym(S): (Trimethylsilyl)ethynyllithium
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 50 ML | 335452-50-ML | In Stock | ₹ 7,761.53 |
| 4 X 25 ML | 335452-4-X-25-ML | In Stock | ₹ 14,754.48 |
335452 - 50 ML
In Stock
Quantity
1
Base Price: ₹ 7,761.53
GST (18%): ₹ 1,397.075
Total Price: ₹ 9,158.605
form
liquid
Quality Level
100
concentration
0.5 M in THF
density
0.88 g/mL at 25 °C
SMILES string
[Li]C#C[Si](C)(C)C
InChI
1S/C5H9Si.Li/c1-5-6(2,3)4;/h2-4H3;
InChI key
ZVXXEONXFWSCIZ-UHFFFAOYSA-N
Related Products
Description
- Application: Lithium (trimethylsilyl)acetylide can be used as a reagent: In the transmetalation and nucleophilic displacement reactions.[1] To prepare propargylic alcohol derivatives by reacting with aldehydes and ketones.[1] To synthesize α,βynones by treating with Weinreb amide or with isoxazolidide.[1] Along with Grignard reagent to convert γ- and δ-thiolactams to thioiminium salts, which are employed as key intermediates to produce disubstituted pyrrolidines.[2]
- Packaging: The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
- Legal Information: Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Supplementary Hazards
EUH019
WGK
WGK 3
Flash Point(F)
-9.4 °F
Flash Point(C)
-23 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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form: liquid
Quality Level: 100
concentration: 0.5 M in THF
density: 0.88 g/mL at 25 °C
SMILES string: [Li]C#C[Si](C)(C)C
InChI: 1S/C5H9Si.Li/c1-5-6(2,3)4;/h2-4H3;
InChI key: ZVXXEONXFWSCIZ-UHFFFAOYSA-N
form:
liquid
Quality Level:
100
concentration:
0.5 M in THF
density:
0.88 g/mL at 25 °C
SMILES string:
[Li]C#C[Si](C)(C)C
InChI:
1S/C5H9Si.Li/c1-5-6(2,3)4;/h2-4H3;
InChI key:
ZVXXEONXFWSCIZ-UHFFFAOYSA-N
form: liquid
Quality Level: 200
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density: __
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