360716

Tris(trimethylsilyl)silane

97%

Manufacturer: Sigma Aldrich

CAS Number: 1873-77-4

Synonym(S): 1,1,1,3,3,3-Hexamethyl-2-trimethylsilyl-trisilane, TTMSS

Select a Size

Pack Size SKU Availability Price
5 G 360716-5-G In Stock ₹ 7,187.80
25 G 360716-25-G In Stock ₹ 20,524.20

360716 - 5 G

₹ 7,187.80

In Stock

Quantity

1

Base Price: ₹ 7,187.80

GST (18%): ₹ 1,293.804

Total Price: ₹ 8,481.604

Quality Level

100

Assay

97%

form

liquid

reaction suitability

reagent type: reductant

refractive index

n20/D 1.489 (lit.)

bp

73 °C/5 mmHg (lit.)

density

0.806 g/mL at 25 °C (lit.)

SMILES string

C[Si](C)(C)[SiH]([Si](C)(C)C)[Si](C)(C)C

InChI

1S/C9H28Si4/c1-11(2,3)10(12(4,5)6)13(7,8)9/h10H,1-9H3

InChI key

SQMFULTZZQBFBM-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
NC2193041
eMolecules​ Tris(trimethylsilyl)silane | 1873-77-4 | MFCD00077893 | 5g
eMolecules​ ₹ 9,824.00
CS-0147249
Tris(trimethylsilyl)silane
ChemScene ₹ 2,652.36 - ₹ 27,293.64
AB80253
1873-77-4 | Tris(trimethylsilyl)silane
A2B Chem ₹ 5,304.72 - ₹ 8,128.20

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Description

  • General description: Tris(trimethylsilyl)silane is an organosilicon generally used as a radical reducing agent for xanthates, organic halides, isocyanides, selenides, and acid chlorides. It is also used for hydrosilylation of alkenes, alkynes, and dialkyl ketones.[1][2][3]
  • Application: Super Silyl Protecting GroupsUsed in:HydrosilylationsRadical reactionsReductions of acid chloridesReductions of carbon-halogen bondsHydrosilations of carbonylsAnother common application involves the use of the tris(trimethylsilyl)silyl (TTMSS, or super silyl) group when complexed with transition metals and main group elementsMore recently, the super silyl group is being utilized in carbon–carbon bond forming reactions

SAFETY INFORMATION

Pictograms

GHS02

Signal Word

Warning

Hazard Statements

H226

Precautionary Statements

P210

Hazard Classifications

Flam. Liq. 3

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Quality Level:
100

Assay:
97%

form:
liquid

reaction suitability:
reagent type: reductant

refractive index:
n20/D 1.489 (lit.)

bp:
73 °C/5 mmHg (lit.)

density:
0.806 g/mL at 25 °C (lit.)

SMILES string:
C[Si](C)(C)[SiH]([Si](C)(C)C)[Si](C)(C)C

InChI:
1S/C9H28Si4/c1-11(2,3)10(12(4,5)6)13(7,8)9/h10H,1-9H3

InChI key:
SQMFULTZZQBFBM-UHFFFAOYSA-N

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SMILES string:
Fc1ccc(cc1)C(Cl)c2ccc(F)cc2

InChI:
1S/C13H9ClF2/c14-13(9-1-5-11(15)6-2-9)10-3-7-12(16)8-4-10/h1-8,13H

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FHPNLCLHMNPLEW-UHFFFAOYSA-N

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