419184

Triphenylphosphine diiodide

technical grade, 90%

Manufacturer: Sigma Aldrich

CAS Number: 6396-07-2

Synonym(S): Diiodotriphenylphosphorane

Select a Size

Pack Size SKU Availability Price
5 G 419184-5-G In Stock ₹ 8,900.00

419184 - 5 G

₹ 8,900.00

In Stock

Quantity

1

Base Price: ₹ 8,900.00

GST (18%): ₹ 1,602.00

Total Price: ₹ 10,502.00

grade

technical grade

Quality Level

100

Assay

90%

form

solid

mp

210-220 °C (lit.)

SMILES string

IP(I)(c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C18H15I2P/c19-21(20,16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

InChI key

NSWZEXJQHIXCFL-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-176-2271
Sigma Aldrich Fine Chemicals Biosciences Triphenylphosphine diiodide technical grade, 90% | Purity: 90% | Mol Wt: 516.09 | 6396-07-2 | MFCD00216568 | 5G
Sigma Aldrich Fine Chemicals Biosciences ₹ 16,979.38
AR003VUW
Triphenylphosphine Diiodide
Aaron Chemicals LLC ₹ 2,823.48 - ₹ 30,202.68
AB80156
6396-07-2 | Diiodotriphenylphosphorane
A2B Chem ₹ 7,187.04 - ₹ 17,796.48

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Description

  • Application: Triphenylphosphine diiodide (Ph3P. I2) can be used as a reagent: To facilitate the conversion of alcohol, thiol, and enol functional groups into alkyl iodides via formation of alkoxyphosphonium iodide.[1] To prepare β-iodo-α,β-unsaturated ketones from cyclic β-diketones in the presence of triethyl amine.[1] In the synthesis of alkyl nitrates from alcohols.[1] In the Beckmann rearrangement reaction to synthesize lactams from cycloalkanone oxime.[1] For the preparation of aromatic and aliphatic carboxylic acid esters in the presence of N,N-dimethylaminopyridine.[2] Ph3P. I2 can also be used to reduce graphene oxide for the production of graphene nanosheets under mild and environmentally friendly conditions.[3]

SAFETY INFORMATION

Pictograms

GHS08,GHS05

Signal Word

Danger

Hazard Statements

H314,H317,H334,H361fd

Precautionary Statements

P202 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Eye Dam. 1 - Repr. 2 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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technical grade

Quality Level:
100

Assay:
90%

form:
solid

mp:
210-220 °C (lit.)

SMILES string:
IP(I)(c1ccccc1)(c2ccccc2)c3ccccc3

InChI:
1S/C18H15I2P/c19-21(20,16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

InChI key:
NSWZEXJQHIXCFL-UHFFFAOYSA-N

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O=C(OCc1ccccc1)C=P(c2ccccc2)(c3ccccc3)c4ccccc4

InChI:
1S/C27H23O2P/c28-27(29-21-23-13-5-1-6-14-23)22-30(24-15-7-2-8-16-24,25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-20,22H,21H2

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INKMLGJBBDRIQR-UHFFFAOYSA-N

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COC(=O)C(Br)CCCC(Br)C(=O)OC

InChI:
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InChI key:
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InChI:
1S/C6H12O6.C2H4O2.Na/c7-1-3(9)5(11)6(12)4(10)2-8;1-2(3)4;/h1,3-6,8-12H,2H2;1H3,(H,3,4);

InChI key:
DPXJVFZANSGRMM-UHFFFAOYSA-N