498033

Cyclohexylzinc bromide solution

0.5 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 7565-57-3

Synonym(S): Cyclohexylzinc(II)bromide

Select a Size

Pack Size SKU Availability Price
50 ML 498033-50-ML In Stock ₹ 21,520.10

498033 - 50 ML

₹ 21,520.10

In Stock

Quantity

1

Base Price: ₹ 21,520.10

GST (18%): ₹ 3,873.618

Total Price: ₹ 25,393.718

Quality Level

100

concentration

0.5 M in THF

density

0.963 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

Br[Zn]C1CCCCC1

InChI

1S/C6H11.BrH.Zn/c1-2-4-6-5-3-1;;/h1H,2-6H2;1H;/q;;+1/p-1

InChI key

XHGMTEIVIUFIPO-UHFFFAOYSA-M

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Description

  • Application: Cyclohexylzinc bromide is an organozinc reagent, generally used in Negishi coupling. Examples include the cross-coupling of alkylzinc halides with aryl/heteroaryl halides using Pd-PEPPSI-IPent[1] and nickel-catalyzed synthesis of 4-substituted coumarins.[2]It can react with the SO2 surrogate, 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct (DABSO) to afford zinc sulfinate salts which can be alkylated to synthesize various useful sulfones.[3]
  • Legal Information: Product of Rieke Metals, Inc. Rieke is a registered trademark of Rieke Metals, Inc.

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H225,H302,H314,H335,H336,H351

Precautionary Statements

P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH014,EUH019

WGK

WGK 3

Flash Point(F)

3.0 °F

Flash Point(C)

-16.1 °C

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storage temp.:
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SMILES string:
Br[Zn]C1CCCCC1

InChI:
1S/C6H11.BrH.Zn/c1-2-4-6-5-3-1;;/h1H,2-6H2;1H;/q;;+1/p-1

InChI key:
XHGMTEIVIUFIPO-UHFFFAOYSA-M

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Br[Zn]C1CCCC1

InChI:
1S/C5H9.BrH.Zn/c1-2-4-5-3-1;;/h1H,2-5H2;1H;/q;;+1/p-1

InChI key:
GOPYCBPMCCJYSN-UHFFFAOYSA-M

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