562076

3,5-Dimethylphenylmagnesium bromide solution

0.5 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 34696-73-6

Select a Size

Pack Size SKU Availability Price
50 ML 562076-50-ML In Stock ₹ 13,866.83

562076 - 50 ML

₹ 13,866.83

In Stock

Quantity

1

Base Price: ₹ 13,866.83

GST (18%): ₹ 2,496.029

Total Price: ₹ 16,362.859

reaction suitability

reaction type: Grignard Reaction

Quality Level

100

concentration

0.5 M in THF

bp

65 °C

density

0.950 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

Cc1cc(C)cc([Mg]Br)c1

InChI

1S/C8H9.BrH.Mg/c1-7-4-3-5-8(2)6-7;;/h4-6H,1-2H3;1H;/q;;+1/p-1

InChI key

XPXQQJMQESWIKM-UHFFFAOYSA-M

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Description

  • Application: 3,5-Dimethylphenylmagnesium bromide solution can be used:As a starting material for the synthesis of diarylborinic acids, which on Suzuki coupling with vinyl triflate yield penultimate methyl ester.[1]To prepare 3,5-dimethyl-p-terphenyl by reacting with biphenylsulfonate in the presence of dppfNiCl2 catalyst.[2]
  • Legal Information: Product of Rieke Metals, Inc. Rieke is a registered trademark of Rieke Metals, Inc.

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS07

Signal Word

Danger

Hazard Statements

H225,H302,H319,H335,H351

Precautionary Statements

P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH019

WGK

WGK 3

Flash Point(F)

-0.0 °F

Flash Point(C)

-17.78 °C

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reaction suitability:
reaction type: Grignard Reaction

Quality Level:
100

concentration:
0.5 M in THF

bp:
65 °C

density:
0.950 g/mL at 25 °C

storage temp.:
2-8°C

SMILES string:
Cc1cc(C)cc([Mg]Br)c1

InChI:
1S/C8H9.BrH.Mg/c1-7-4-3-5-8(2)6-7;;/h4-6H,1-2H3;1H;/q;;+1/p-1

InChI key:
XPXQQJMQESWIKM-UHFFFAOYSA-M

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bp:
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storage temp.:
2-8°C

SMILES string:
COc1cccc(C[Mg]Cl)c1

InChI:
1S/C8H9O.ClH.Mg/c1-7-4-3-5-8(6-7)9-2;;/h3-6H,1H2,2H3;1H;/q;;+1/p-1

InChI key:
ZPCUEMLXJGELGI-UHFFFAOYSA-M

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SMILES string:
COc1ccccc1C[Mg]Cl

InChI:
1S/C8H9O.ClH.Mg/c1-7-5-3-4-6-8(7)9-2;;/h3-6H,1H2,2H3;1H;/q;;+1/p-1

InChI key:
JJNLSBBAAQTDSM-UHFFFAOYSA-M