563749
9-Phenanthrylmagnesium bromide
0.5 M in THF
Manufacturer: Sigma Aldrich
CAS Number: 71112-64-6
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 50 ML | 563749-50-ML | In Stock | ₹ 19,669.03 |
563749 - 50 ML
In Stock
Quantity
1
Base Price: ₹ 19,669.03
GST (18%): ₹ 3,540.425
Total Price: ₹ 23,209.455
reaction suitability
reaction type: Grignard Reaction
Quality Level
100
concentration
0.5 M in THF
bp
65 °C (lit.)
density
0.970 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
Br[Mg]c1cc2ccccc2c3ccccc13
InChI
1S/C14H9.BrH.Mg/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13;;/h1-9H;1H;/q;;+1/p-1
InChI key
ACMUZKQPXSHTGB-UHFFFAOYSA-M
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | eMolecules Synthonix - Stock 9-Phenanthrylmagnesium bromide 0.5 M in THF 50ml 437237396 P31721 71112-64-6 MFCD00672008 281.435 C14H9BrMg | eMolecules | ₹ 34,886.23 | |
 | eMolecules Synthonix - Stock 9-Phenanthrylmagnesium bromide 0.5 M in THF 100ml 437237397 P31721 71112-64-6 MFCD00672008 281.435 C14H9BrMg | eMolecules | ₹ 59,980.13 | |
 | Sigma Aldrich Fine Chemicals Biosciences 9-Phenanthrylmagnesium bromide 0.5 M in THF | 71112-64-6 | MFCD00672008 | 50ML | Sigma Aldrich Fine Chemicals Biosciences | ₹ 38,780.07 | |
 | 71112-64-6 | 9-Phenanthrylmagnesium bromide | A2B Chem | ₹ 29,432.64 - ₹ 48,683.64 |
Related Products
Description
- General description: 9-phenanthrylmagnesium bromide is a Grignard reagent. It can be prepared using magnesium turnings and 9-bromophenanthrene under anhydrous condition.[1]
- Application: 9-Phenanthrylmagnesium bromide can be used as a reagent to prepare: 9-alkyl and 9-arylthiophenanthrenes by reacting with alkyl or aryl thiol compounds.[2] (S)-α-methylbenzyl 1-(9-phenanthryl)-2-naphthoate by treating with (S)- α -methylbenzyl methoxy-2-naphthoate.[3] 1-(9-Phenanthryl)-1-phenylethanol (carbinol) by reacting with acetophenone. The obtained carbinol undergoes dehydration reaction in the presence of acetic acid and sulfuric acid to afford 1-(9-phenanthryl)-1-phenylethene (PPE).[4]
- Legal Information: Product of Rieke Metals, Inc. Rieke is a registered trademark of Rieke Metals, Inc.
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
Target Organs
Respiratory system
Supplementary Hazards
EUH019
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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reaction suitability: reaction type: Grignard Reaction
Quality Level: 100
concentration: 0.5 M in THF
bp: 65 °C (lit.)
density: 0.970 g/mL at 25 °C (lit.)
storage temp.: 2-8°C
SMILES string: Br[Mg]c1cc2ccccc2c3ccccc13
InChI: 1S/C14H9.BrH.Mg/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13;;/h1-9H;1H;/q;;+1/p-1
InChI key: ACMUZKQPXSHTGB-UHFFFAOYSA-M
reaction suitability:
reaction type: Grignard Reaction
Quality Level:
100
concentration:
0.5 M in THF
bp:
65 °C (lit.)
density:
0.970 g/mL at 25 °C (lit.)
storage temp.:
2-8°C
SMILES string:
Br[Mg]c1cc2ccccc2c3ccccc13
InChI:
1S/C14H9.BrH.Mg/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13;;/h1-9H;1H;/q;;+1/p-1
InChI key:
ACMUZKQPXSHTGB-UHFFFAOYSA-M
reaction suitability: reaction type: Grignard Reaction
Quality Level: 100
concentration: 0.5 M in THF
bp: 65 °C (lit.)
density: 0.948 g/mL at 25 °C (lit.)
storage temp.: 2-8°C
SMILES string: Cc1cccc([Mg]Br)c1C
InChI: 1S/C8H9.BrH.Mg/c1-7-5-3-4-6-8(7)2;;/h3-5H,1-2H3;1H;/q;;+1/p-1
InChI key: GWICKWUOSJJCNO-UHFFFAOYSA-M
reaction suitability:
reaction type: Grignard Reaction
Quality Level:
100
concentration:
0.5 M in THF
bp:
65 °C (lit.)
density:
0.948 g/mL at 25 °C (lit.)
storage temp.:
2-8°C
SMILES string:
Cc1cccc([Mg]Br)c1C
InChI:
1S/C8H9.BrH.Mg/c1-7-5-3-4-6-8(7)2;;/h3-5H,1-2H3;1H;/q;;+1/p-1
InChI key:
GWICKWUOSJJCNO-UHFFFAOYSA-M
reaction suitability: reaction type: Grignard Reaction
Quality Level: 100
concentration: 0.5 M in THF
bp: 65 °C (lit.)
density: 0.945 g/mL at 25 °C (lit.)
storage temp.: 2-8°C
SMILES string: Cc1ccc(C)c([Mg]Br)c1
InChI: 1S/C8H9.BrH.Mg/c1-7-3-5-8(2)6-4-7;;/h3-5H,1-2H3;1H;/q;;+1/p-1
InChI key: XYLKRQFNMXVTLQ-UHFFFAOYSA-M
reaction suitability:
reaction type: Grignard Reaction
Quality Level:
100
concentration:
0.5 M in THF
bp:
65 °C (lit.)
density:
0.945 g/mL at 25 °C (lit.)
storage temp.:
2-8°C
SMILES string:
Cc1ccc(C)c([Mg]Br)c1
InChI:
1S/C8H9.BrH.Mg/c1-7-3-5-8(2)6-4-7;;/h3-5H,1-2H3;1H;/q;;+1/p-1
InChI key:
XYLKRQFNMXVTLQ-UHFFFAOYSA-M
reaction suitability: reaction type: Grignard Reaction
Quality Level: 100
concentration: 0.5 M in THF
bp: 65 °C (lit.)
density: 0.918 g/mL at 25 °C (lit.)
storage temp.: 2-8°C
SMILES string: Cc1ccc(C[Mg]Cl)cc1
InChI: 1S/C8H9.ClH.Mg/c1-7-3-5-8(2)6-4-7;;/h3-6H,1H2,2H3;1H;/q;;+1/p-1
InChI key: SAKYCLWKOWGTFT-UHFFFAOYSA-M
reaction suitability:
reaction type: Grignard Reaction
Quality Level:
100
concentration:
0.5 M in THF
bp:
65 °C (lit.)
density:
0.918 g/mL at 25 °C (lit.)
storage temp.:
2-8°C
SMILES string:
Cc1ccc(C[Mg]Cl)cc1
InChI:
1S/C8H9.ClH.Mg/c1-7-3-5-8(2)6-4-7;;/h3-6H,1H2,2H3;1H;/q;;+1/p-1
InChI key:
SAKYCLWKOWGTFT-UHFFFAOYSA-M