754242

Tetrahydroxydiboron

95%

Manufacturer: Sigma Aldrich

CAS Number: 13675-18-8

Synonym(S): BBA, Bis-Boric acid, Diboronic acid

Select a Size

Pack Size SKU Availability Price
1 G 754242-1-G In Stock ₹ 4,037.73
100 G 754242-100-G In Stock ₹ 65,437.13

754242 - 1 G

₹ 4,037.73

In Stock

Quantity

1

Base Price: ₹ 4,037.73

GST (18%): ₹ 726.791

Total Price: ₹ 4,764.521

Quality Level

200

Assay

95%

form

solid

mp

>385 °C

SMILES string

OB(O)B(O)O

InChI

1S/B2H4O4/c3-1(4)2(5)6/h3-6H

InChI key

SKOWZLGOFVSKLB-UHFFFAOYSA-N

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Description

  • Application: Tetrahydroxydiboron (BBA) is an efficient borylating agent that can be used to borylate a wide variety of aryl and heteroaryl substrates with low Pd- and Ni-catalyst loads.[1][2]Other reactions employing BBA as a reagent:Palladium-catalyzed boronation of vinyl cyclopropane, vinyl aziridine, and allyl acetate substrates.[3]To facilitate catalytic transfer hydrogenations of simple alkenes and alkynes.[4]Selective reducing agent for in situ N-oxide reduction of pyridine-N-oxides.[5]As a substitute to bis(pinacolato) diboron for Miyaura borylation.[6]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H302 + H332,H315,H319,H335

Precautionary Statements

P261 - P264 - P301 + P312 - P302 + P352 - P304 + P340 + P312 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable