775797

Isopropylmagnesium bromide solution

0.75 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 920-39-8

Synonym(S): 1-Methylethylmagnesium bromide, 2-Propylmagnesium bromide, iso-Propylmagnesium bromide, Bromoisopropylmagnesium

Select a Size

Pack Size SKU Availability Price
4 X 25 ML 775797-4-X-25-ML In Stock ₹ 8,984.75
100 ML 775797-100-ML In Stock ₹ 9,450.23
800 ML 775797-800-ML In Stock ₹ 29,747.10

775797 - 4 X 25 ML

₹ 8,984.75

In Stock

Quantity

1

Base Price: ₹ 8,984.75

GST (18%): ₹ 1,617.255

Total Price: ₹ 10,602.005

form

solution

Quality Level

100

reaction suitability

reaction type: Grignard Reaction

concentration

0.75 M in THF

density

0.982 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(C)[Mg]Br

InChI

1S/C3H7.BrH.Mg/c1-3-2;;/h3H,1-2H3;1H;/q;;+1/p-1

InChI key

UCJIVFREPMUZDC-UHFFFAOYSA-M

Other Options

Image Product Name Manufacturer Price Range
703567
Isopropylmagnesium bromide solution
Sigma Aldrich ₹ 16,172.55
AB46331
920-39-8 | Isopropylmagnesium Bromide
A2B Chem ₹ 8,556.00

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Description

  • Application: Preparation of isopropylmagnesium bromide solutions: In this study, various concentrations of isopropylmagnesium bromide solutions were prepared, detailing their stability and reactivity for use in palladium-catalyzed cross-coupling reactions and other synthetic applications (Vulović et al., 2017). Reductive coupling of amides: This research discusses the reductive functionalization of tertiary amides using isopropylmagnesium bromide, providing a novel method for amine synthesis, which is crucial for pharmaceutical chemistry (Xie and Dixon, 2017). Synthesis of 1, 2, 3-triazoles: The study explores the use of isopropylmagnesium bromide in the synthesis of 1, 2, 3-triazoles through Grignard reactions, highlighting its role in protecting azides during the reaction process (Namioka et al., 2023). Disposable cartridge concept for Grignard reagents: This paper introduces a novel disposable cartridge for the on-demand synthesis of Grignard reagents, including isopropylmagnesium bromide, enhancing the safety and scalability of Grignard reactions (Berton et al., 2020).
  • Packaging: The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
  • Legal Information: Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H225,H260,H302,H314,H335,H336,H351

Precautionary Statements

P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

Target Organs

Respiratory system

Supplementary Hazards

EUH014,EUH019

WGK

WGK 1

Flash Point(F)

closed cup

Flash Point(C)

closed cup

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form:
solution

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concentration:
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density:
0.982 g/mL at 25 °C

storage temp.:
2-8°C

SMILES string:
CC(C)[Mg]Br

InChI:
1S/C3H7.BrH.Mg/c1-3-2;;/h3H,1-2H3;1H;/q;;+1/p-1

InChI key:
UCJIVFREPMUZDC-UHFFFAOYSA-M

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SMILES string:
CC(C)C(CC)CCC(C)C1CCC2C3CC=C4CC(OC(CCC(OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOC)=O)=O)CCC4(C)C3CCC21C

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CC(C)C(CC)CCC(C)C1CCC2C3CC=C4CC(OC(CCC(OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOC)=O)=O)CCC4(C)C3CCC21C

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