796549

Stahl Aerobic Oxidation TEMPO solution

0.2 M in acetonitrile, Solution for Oxidation of Primary Alcohols

Manufacturer: Sigma Aldrich

Select a Size

Pack Size SKU Availability Price
25 ML 796549-25-ML In Stock ₹ 9,547.65

796549 - 25 ML

₹ 9,547.65

In Stock

Quantity

1

Base Price: ₹ 9,547.65

GST (18%): ₹ 1,718.577

Total Price: ₹ 11,266.227

Quality Level

100

form

liquid

reaction suitability

reagent type: oxidant

concentration

0.2 M in acetonitrile

storage temp.

2-8°C

SMILES string

CN1C=CN=C1.CC2(C)CCCC(C)(C)N2[O].C3(C4=NC=CC=C4)=NC=CC=C3

InChI

1S/C10H8N2.C9H18NO.C4H6N2/c1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-8(2)6-5-7-9(3,4)10(8)11;1-6-3-2-5-4-6/h1-8H;5-7H2,1-4H3;2-4H,1H3

InChI key

BQFURWVGIDXRNB-UHFFFAOYSA-N

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Description

  • General description: Stahl Aerobic Oxidation TEMPO solution contains 1-methylimidazole (NMI), 2,2′-bipyridyl (bpy), and TEMPO. It is widely employed for the oxidation of alcohols.
  • Application: This convenience solution can be used in tandem with tetrakisacetonitrile copper(I) triflate (685038) for the oxidation of primary alcohols through aerobic conditions developed by the Stahl Research Group.
  • Other Notes: Technology Spotlight: Aerobic Alcohol Oxidation SolutionsStable TEMPO and ABNO Catalyst Solutions for User-Friendly (bpy)Cu/Nitroxyl- Catalyzed Aerobic Alcohol OxidationPractical Aerobic Alcohol Oxidation with Cu/Nitroxyl and Nitroxyl/NOx Catalyst Systems

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H225,H302 + H312 + H332,H314,H361d

Precautionary Statements

P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1C

WGK

WGK 3

Flash Point(F)

35.6 °F

Flash Point(C)

2.0 °C