796549
Stahl Aerobic Oxidation TEMPO solution
0.2 M in acetonitrile, Solution for Oxidation of Primary Alcohols
Manufacturer: Sigma Aldrich
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 25 ML | 796549-25-ML | In Stock | ₹ 9,547.65 |
796549 - 25 ML
In Stock
Quantity
1
Base Price: ₹ 9,547.65
GST (18%): ₹ 1,718.577
Total Price: ₹ 11,266.227
Quality Level
100
form
liquid
reaction suitability
reagent type: oxidant
concentration
0.2 M in acetonitrile
storage temp.
2-8°C
SMILES string
CN1C=CN=C1.CC2(C)CCCC(C)(C)N2[O].C3(C4=NC=CC=C4)=NC=CC=C3
InChI
1S/C10H8N2.C9H18NO.C4H6N2/c1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-8(2)6-5-7-9(3,4)10(8)11;1-6-3-2-5-4-6/h1-8H;5-7H2,1-4H3;2-4H,1H3
InChI key
BQFURWVGIDXRNB-UHFFFAOYSA-N
Related Products
Description
- General description: Stahl Aerobic Oxidation TEMPO solution contains 1-methylimidazole (NMI), 2,2′-bipyridyl (bpy), and TEMPO. It is widely employed for the oxidation of alcohols.
- Application: This convenience solution can be used in tandem with tetrakisacetonitrile copper(I) triflate (685038) for the oxidation of primary alcohols through aerobic conditions developed by the Stahl Research Group.
- Other Notes: Technology Spotlight: Aerobic Alcohol Oxidation SolutionsStable TEMPO and ABNO Catalyst Solutions for User-Friendly (bpy)Cu/Nitroxyl- Catalyzed Aerobic Alcohol OxidationPractical Aerobic Alcohol Oxidation with Cu/Nitroxyl and Nitroxyl/NOx Catalyst Systems
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1C
WGK
WGK 3
Flash Point(F)
35.6 °F
Flash Point(C)
2.0 °C
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Quality Level: 100
form: liquid
reaction suitability: reagent type: oxidant
concentration: 0.2 M in acetonitrile
storage temp.: 2-8°C
SMILES string: CN1C=CN=C1.CC2(C)CCCC(C)(C)N2[O].C3(C4=NC=CC=C4)=NC=CC=C3
InChI: 1S/C10H8N2.C9H18NO.C4H6N2/c1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-8(2)6-5-7-9(3,4)10(8)11;1-6-3-2-5-4-6/h1-8H;5-7H2,1-4H3;2-4H,1H3
InChI key: BQFURWVGIDXRNB-UHFFFAOYSA-N
Quality Level:
100
form:
liquid
reaction suitability:
reagent type: oxidant
concentration:
0.2 M in acetonitrile
storage temp.:
2-8°C
SMILES string:
CN1C=CN=C1.CC2(C)CCCC(C)(C)N2[O].C3(C4=NC=CC=C4)=NC=CC=C3
InChI:
1S/C10H8N2.C9H18NO.C4H6N2/c1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-8(2)6-5-7-9(3,4)10(8)11;1-6-3-2-5-4-6/h1-8H;5-7H2,1-4H3;2-4H,1H3
InChI key:
BQFURWVGIDXRNB-UHFFFAOYSA-N
Quality Level: 100
form: liquid
reaction suitability: reagent type: oxidant
concentration: __
storage temp.: 2-8°C
SMILES string: __
InChI: __
InChI key: __
Quality Level:
100
form:
liquid
reaction suitability:
reagent type: oxidant
concentration:
__
storage temp.:
2-8°C
SMILES string:
__
InChI:
__
InChI key:
__
Quality Level: 100
form: liquid
reaction suitability: __
concentration: __
storage temp.: __
SMILES string: C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1
InChI: 1S/C12H36O6Si6/c1-19(2)13-20(3,4)15-22(7,8)17-24(11,12)18-23(9,10)16-21(5,6)14-19/h1-12H3
InChI key: IUMSDRXLFWAGNT-UHFFFAOYSA-N
Quality Level:
100
form:
liquid
reaction suitability:
__
concentration:
__
storage temp.:
__
SMILES string:
C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1
InChI:
1S/C12H36O6Si6/c1-19(2)13-20(3,4)15-22(7,8)17-24(11,12)18-23(9,10)16-21(5,6)14-19/h1-12H3
InChI key:
IUMSDRXLFWAGNT-UHFFFAOYSA-N
Quality Level: 100
form: powder or crystals
reaction suitability: __
concentration: __
storage temp.: __
SMILES string: NC(COP(O)(O)=O)C(O)=O
InChI: 1S/C3H8NO6P/c4-2(3(5)6)1-10-11(7,8)9/h2H,1,4H2,(H,5,6)(H2,7,8,9)
InChI key: BZQFBWGGLXLEPQ-UHFFFAOYSA-N
Quality Level:
100
form:
powder or crystals
reaction suitability:
__
concentration:
__
storage temp.:
__
SMILES string:
NC(COP(O)(O)=O)C(O)=O
InChI:
1S/C3H8NO6P/c4-2(3(5)6)1-10-11(7,8)9/h2H,1,4H2,(H,5,6)(H2,7,8,9)
InChI key:
BZQFBWGGLXLEPQ-UHFFFAOYSA-N