901251

[2,2′-Bipyridine]-6-carboxylic acid hydrochloride

Manufacturer: Sigma Aldrich

CAS Number: 4392-87-4

Synonym(S): PPA directing group

Select a Size

Pack Size SKU Availability Price
500 MG 901251-500-MG In Stock ₹ 14,289.00

901251 - 500 MG

₹ 14,289.00

In Stock

Quantity

1

Base Price: ₹ 14,289.00

GST (18%): ₹ 2,572.02

Total Price: ₹ 16,861.02

form

powder or crystals

Quality Level

100

reaction suitability

reaction type: C-C Bond Formationreagent type: catalystreagent type: ligandreaction type: C-H Activation

InChI

1S/C11H8N2O2/c14-11(15)10-6-3-5-9(13-10)8-4-1-2-7-12-8/h1-7H,(H,14,15)

InChI key

ZQTILGDVDYWICD-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-248-5847
eMolecules​ Ambeed / [22-Bipyridine]-6-carboxylic acid / 100mg / 525101020 / A183618 / / 4392-87-4 / MFCD11100046 / 200.197 / C11H8N2O2
eMolecules​ ₹ 3,555.02
50-174-2745
Sigma Aldrich Fine Chemicals Biosciences [2,2'-Bipyridine]-6-carboxylic acid hydrochloride | 4392-87-4 (free base) | MFCD11100046 | 500MG
Sigma Aldrich Fine Chemicals Biosciences ₹ 17,398.63
AR003AZO
[2,2'-Bipyridine]-6-carboxylic acid
Aaron Chemicals LLC ₹ 1,882.32 - ₹ 48,426.96
AB53112
4392-87-4 | [2,2'-Bipyridine]-6-carboxylic acid
A2B Chem ₹ 1,454.52 - ₹ 6,673.68

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Description

  • Application: Developed in the Engle lab, this 2,2′-bipyridylamide (PPA) is a pincer-like, removable tridentate directing group that stabilizes 6-membered palladacycles for olefin functionalization. Together with similar ligand PAQ (901250), researchers demonstrated regioselective remote hydrocarbofunctionalization of alkene-containing substrate classes (e.g. 4-pentenoic acids, allylic alcohols, homoallyl amines, bis-homoallylamines) using Pd(II) catalysis.
  • Other Notes: Tridentate Directing Groups Stabilize 6-Membered Palladacycles in Catalytic Alkene Hydrofunctionalization

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Compare Similar Items

Show Difference

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Sigma Aldrich

901251

--


form:
powder or crystals

Quality Level:
100

reaction suitability:
reaction type: C-C Bond Formationreagent type: catalystreagent type: ligandreaction type: C-H Activation

InChI:
1S/C11H8N2O2/c14-11(15)10-6-3-5-9(13-10)8-4-1-2-7-12-8/h1-7H,(H,14,15)

InChI key:
ZQTILGDVDYWICD-UHFFFAOYSA-N

Img

Sigma Aldrich

901252

≥98%...


form:
powder or crystals

Quality Level:
100

reaction suitability:
__

InChI:
1S/C8H11N.ClH/c1-6-4-3-5-7(2)8(6)9;/h3-5H,9H2,1-2H3;1H

InChI key:
QNWMFJDRMZWZNN-UHFFFAOYSA-N

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Sigma Aldrich

901255

≥95%...


form:
liquid

Quality Level:
100

reaction suitability:
__

InChI:
1S/C5H12O2/c1-3-7-4-5(2)6/h5-6H,3-4H2,1-2H3

InChI key:
JOLQKTGDSGKSKJ-UHFFFAOYSA-N

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Sigma Aldrich

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--


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powder or crystals

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__

InChI:
__

InChI key:
__