925446
5-Vinylthianthrenium tetrafluoroborate
≥95%
Manufacturer: Sigma Aldrich
CAS Number: 2703016-98-0
Synonym(S): Vinyl-TT
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 500 MG | 925446-500-MG | In Stock | ₹ 23,440.00 |
| 2 G | 925446-2-G | In Stock | ₹ 53,690.00 |
925446 - 500 MG
In Stock
Quantity
1
Base Price: ₹ 23,440.00
GST (18%): ₹ 4,219.20
Total Price: ₹ 27,659.20
Quality Level
100
Assay
≥95%
form
powder
reaction suitability
reaction type: C-C Bond Formation
mp
110-112 °C
storage temp.
−20°C
SMILES string
[F-][B+3]([F-])([F-])[F-].S1C=2C=CC=CC2[S+](C=C)C=3C=CC=CC13
InChI
1S/C14H11S2.BF4/c1-2-16-13-9-5-3-7-11(13)15-12-8-4-6-10-14(12)16;2-1(3,4)5/h2-10H,1H2;/q+1;-1
InChI key
FXHBWPNFHMRFKM-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | 2703016-98-0 | 5-ethenyl-5H-thianthren-5-ium,tetrafluoroboranuide | A2B Chem | ₹ 12,063.96 - ₹ 1,30,307.88 |
Related Products
Description
- Application: 5-Vinylthianthrenium tetrafluoroborate is a crystalline, shelf-stable vinylating reagent developed by the Ritter Lab. Despite the great functionality of the vinyl group for diversification of target compounds, the selective installation of this moeity has remained challenging. 5-Vinylthianthrenium tetrafluoroborate can perform this otherwise challenging transformation with a broad scope of substrate, including the N-vinylation of heterocycles, vinylation of aryl boronic acids, and the annulation of cyclic and heterocyclic substrates. Additionally, this reagent can be used to enable palladium catalyzed cross-coupling reactions. The functionality of 5-vinylthianthrenium tetrafluoroborate enables the usage of vinyl groups as a versatile tool for further functionalization of many substrates and is a functional tool for many snythetic pathways.
- Other Notes: Chemoselective umpolung of thiols to episulfoniums for cysteine bioconjugation
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Quality Level: 100
Assay: ≥95%
form: powder
reaction suitability: reaction type: C-C Bond Formation
mp: 110-112 °C
storage temp.: −20°C
SMILES string: [F-][B+3]([F-])([F-])[F-].S1C=2C=CC=CC2[S+](C=C)C=3C=CC=CC13
InChI: 1S/C14H11S2.BF4/c1-2-16-13-9-5-3-7-11(13)15-12-8-4-6-10-14(12)16;2-1(3,4)5/h2-10H,1H2;/q+1;-1
InChI key: FXHBWPNFHMRFKM-UHFFFAOYSA-N
Quality Level:
100
Assay:
≥95%
form:
powder
reaction suitability:
reaction type: C-C Bond Formation
mp:
110-112 °C
storage temp.:
−20°C
SMILES string:
[F-][B+3]([F-])([F-])[F-].S1C=2C=CC=CC2[S+](C=C)C=3C=CC=CC13
InChI:
1S/C14H11S2.BF4/c1-2-16-13-9-5-3-7-11(13)15-12-8-4-6-10-14(12)16;2-1(3,4)5/h2-10H,1H2;/q+1;-1
InChI key:
FXHBWPNFHMRFKM-UHFFFAOYSA-N
Quality Level: 100
Assay: __
form: powder
reaction suitability: reagent type: catalystreaction type: Cross Couplings
mp: __
storage temp.: __
SMILES string: Br[Pd](C1=CC=C(C=C1)C(F)(F)F)P(C(C(OC)=CC=C2OC)=C2C(C(C(C)C)=CC(C(C)C)=C3)=C3C(C)C)(C4CCCCC4)C56C[C@H]7C[C@H](C[C@H](C7)C6)C5
InChI: __
InChI key: __
Quality Level:
100
Assay:
__
form:
powder
reaction suitability:
reagent type: catalystreaction type: Cross Couplings
mp:
__
storage temp.:
__
SMILES string:
Br[Pd](C1=CC=C(C=C1)C(F)(F)F)P(C(C(OC)=CC=C2OC)=C2C(C(C(C)C)=CC(C(C)C)=C3)=C3C(C)C)(C4CCCCC4)C56C[C@H]7C[C@H](C[C@H](C7)C6)C5
InChI:
__
InChI key:
__
Quality Level: 100
Assay: __
form: __
reaction suitability: __
mp: __
storage temp.: −20°C
SMILES string: __
InChI: __
InChI key: __
Quality Level:
100
Assay:
__
form:
__
reaction suitability:
__
mp:
__
storage temp.:
−20°C
SMILES string:
__
InChI:
__
InChI key:
__
Quality Level: 100
Assay: ≥95%
form: powder
reaction suitability: reagent type: catalystreaction type: Cross Couplings
mp: >300 °C
storage temp.: __
SMILES string: __
InChI: __
InChI key: __
Quality Level:
100
Assay:
≥95%
form:
powder
reaction suitability:
reagent type: catalystreaction type: Cross Couplings
mp:
>300 °C
storage temp.:
__
SMILES string:
__
InChI:
__
InChI key:
__