920398

Lithium bis(trimethylsilyl)amide

99.9% trace metals basis

Manufacturer: Sigma Aldrich

CAS Number: 4039-32-1

Synonym(S): LHMDS, LiHMDS, LiTMSA, Lithium hexamethyldisilazide, Hexamethyldisilazane lithium salt

Select a Size

Pack Size SKU Availability Price
1 G 920398-1-G In Stock ₹ 2,565.53
25 G 920398-25-G In Stock ₹ 6,646.55
100 G 920398-100-G In Stock ₹ 18,489.10

920398 - 1 G

₹ 2,565.53

In Stock

Quantity

1

Base Price: ₹ 2,565.53

GST (18%): ₹ 461.795

Total Price: ₹ 3,027.325

Quality Level

200

Assay

99.9% trace metals basis

form

solid

density

0.860 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

[Li]N([Si](C)(C)C)[Si](C)(C)C

InChI

1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1

InChI key

YNESATAKKCNGOF-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-165-6996
Sigma Aldrich Fine Chemicals Biosciences Lithium bis(trimethylsilyl)amide solution 1.0M in THF, 4039-32-1, MFCD00008261
Sigma Aldrich Fine Chemicals Biosciences ₹ 7,905.74
50-165-6997
Sigma Aldrich Fine Chemicals Biosciences Lithium bis(trimethylsilyl)amide solution, 4039-32-1, MFCD00008261, 100mL
Sigma Aldrich Fine Chemicals Biosciences ₹ 8,247.98
501838042
Sigma Aldrich Fine Chemicals Biosciences Lithium bis(trimethylsilyl)amide solution 1 M in toluene | 4039-32-1 | MFCD00008261 | 100ML
Sigma Aldrich Fine Chemicals Biosciences ₹ 7,922.86
501838035
Sigma Aldrich Fine Chemicals Biosciences Lithium bis(trimethylsilyl)amide solution 1.0 M in THF | 4039-32-1 | MFCD00008261 | 1L
Sigma Aldrich Fine Chemicals Biosciences ₹ 38,360.83
501838036
Sigma Aldrich Fine Chemicals Biosciences Lithium bis(trimethylsilyl)amide solution, 1.0 M in THF | 4039-32-1 | MFCD00008261 | 2X2ML
Sigma Aldrich Fine Chemicals Biosciences ₹ 3,276.95
501838040
Sigma Aldrich Fine Chemicals Biosciences Lithium bis(trimethylsilyl)amide 97% | 4039-32-1 | MFCD00008261 | 50G
Sigma Aldrich Fine Chemicals Biosciences ₹ 14,359.53
501838048
Sigma Aldrich Fine Chemicals Biosciences Lithium bis(trimethylsilyl)amide solution 0.5 M in 2-methyltetrahydrofuran | 4039-32-1 | MFCD00008261 | 100ML
Sigma Aldrich Fine Chemicals Biosciences ₹ 11,948.45
501838049
Sigma Aldrich Fine Chemicals Biosciences Lithium bis(trimethylsilyl)amide solution 0.5 M in 2-methyltetrahydrofuran | 4039-32-1 | MFCD00008261 | 4X25ML
Sigma Aldrich Fine Chemicals Biosciences ₹ 11,424.83
501838031
Sigma Aldrich Fine Chemicals Biosciences Lithium bis(trimethylsilyl)amide solution | 4039-32-1 | MFCD00008261 | 100ml
Sigma Aldrich Fine Chemicals Biosciences ₹ 10,900.34
501838038
Sigma Aldrich Fine Chemicals Biosciences Lithium bis(trimethylsilyl)amide | 4039-32-1 | MFCD00008261 | 10g
Sigma Aldrich Fine Chemicals Biosciences ₹ 11,424.83

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Description

  • General description: Lithium bis(trimethylsilyl)amide also known as lithium hexamethyldisilazide (LiHMDS) is a non-nucleophilic strong base. It exhibits ionic conductivity and is widely used as a lithium source and additive in electrolyte formulations for lithium-ion batteries.
  • Application: Lithium bis(trimethylsilyl)amide can be used:As an electrolyte additive for non-aqueous lithium metal batteries. LiHMDS acts as a scavenger for hydrofluoric acid and forms an electrochemical robust cathode|electrolyte interphase (CEI) and suppresses the side reactions with the electrolyte solution.[1]As a lithium precursor for atomic layer deposition(ALD) of textured Li4Ti5O12 as anode material for Li-ion ultrafast charging thin-film batteries. It enables the controlled delivery of lithium atoms into the deposition process, leading to the growth of thin films with precise thickness and composition.[2]As a precursor to fabricate in situ lithiated quinone cathode as high-capacity organic electrode material for all-solid-state thin-film battery setup.[3]

SAFETY INFORMATION

Pictograms

GHS02,GHS05

Signal Word

Danger

Hazard Statements

H228,H251,H314

Precautionary Statements

P210 - P235 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 1 - Skin Corr. 1B

Supplementary Hazards

EUH014

WGK

WGK 2

Flash Point(F)

62.6 °F

Flash Point(C)

17 °C

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[Li]N([Si](C)(C)C)[Si](C)(C)C

InChI:
1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1

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YNESATAKKCNGOF-UHFFFAOYSA-N

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