373710

Molybdenum(VI) dichloride dioxide

Manufacturer: Sigma Aldrich

CAS Number: 13637-68-8

Synonym(S): Dichlorodioxomolybdenum

Select a Size

Pack Size SKU Availability Price
1 G 373710-1-G In Stock ₹ 5,423.33
10 G 373710-10-G In Stock ₹ 40,269.00

373710 - 1 G

₹ 5,423.33

In Stock

Quantity

1

Base Price: ₹ 5,423.33

GST (18%): ₹ 976.199

Total Price: ₹ 6,399.529

form

flakes

Quality Level

100

concentration

34.4-36.9% chloride (silver nitrate titration)

density

3.31 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

Cl[Mo](Cl)(=O)=O

InChI

1S/2ClH.Mo.2O/h2*1H;;;/q;;+2;;/p-2

InChI key

JCFNAADCQWXIJD-UHFFFAOYSA-L

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Description

  • General description: Molybdenum(VI) dichloride dioxide is an oxo-halide of molybdenum widely used as a catalyst for various organic transformations. It is an oxo-transfer catalyst that has the ability to promote oxidation as well as reduction reactions. It can also be used as a chemical vapor deposition(CVD) precursor to synthesize various Mo-based nanomaterials.[1] [2]
  • Application: [3]Molybdenum(VI) dichloride dioxide can be used as a catalyst:For thioacetalization of heterocyclic, aromatic, and aliphatic compounds.[1]To synthesize mono-, di-, tri-, and tetracarbamates from alcohols and aromatic or aliphatic isocyanates.[4]For stereospecific deoxygenation of epoxides to alkenes.[5]For the synthesis of dihydropyrimidinone/thione and polyhydroquinoline derivatives via a Biginelli and Hantzsch reaction.[3]It can also be used as a precursor to synthesize MoO2 nanoparticles.[2]

SAFETY INFORMATION

Pictograms

GHS05

Signal Word

Danger

Hazard Statements

H314

Precautionary Statements

P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363

Hazard Classifications

Skin Corr. 1B

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

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Sigma Aldrich

373710

--


form:
flakes

Quality Level:
100

concentration:
34.4-36.9% chloride (silver nitrate titration)

density:
3.31 g/mL at 25 °C (lit.)

application(s):
battery manufacturing

SMILES string:
Cl[Mo](Cl)(=O)=O

InChI:
1S/2ClH.Mo.2O/h2*1H;;;/q;;+2;;/p-2

InChI key:
JCFNAADCQWXIJD-UHFFFAOYSA-L

Img

Sigma Aldrich

373729

97%...


form:
powder or crystals

Quality Level:
100

concentration:
__

density:
__

application(s):
__

SMILES string:
Cl[Mo](Cl)(Cl)(Cl)=O

InChI:
1S/4ClH.Mo.O/h4*1H;;/q;;;;+4;/p-4

InChI key:
UYEGPKGLVUUIGD-UHFFFAOYSA-J

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Sigma Aldrich

373753

96%...


form:
liquid

Quality Level:
100

concentration:
__

density:
0.851 g/mL at 25 °C (lit.)

application(s):
__

SMILES string:
[H]C(=O)C[C@@H](C)CC\C=C(\C)C

InChI:
1S/C10H18O/c1-9(2)5-4-6-10(3)7-8-11/h5,8,10H,4,6-7H2,1-3H3/t10-/m0/s1

InChI key:
NEHNMFOYXAPHSD-JTQLQIEISA-N

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Sigma Aldrich

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contains 50-200 ppm MEHQ as inhibit...


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liquid

Quality Level:
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__

density:
1.181 g/mL at 25 °C (lit.)

application(s):
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SMILES string:
CC(=C)C(=O)OCC(F)(F)F

InChI:
1S/C6H7F3O2/c1-4(2)5(10)11-3-6(7,8)9/h1,3H2,2H3

InChI key:
__