Ammonium cerium(IV) nitrate
puriss. p.a., ACS reagent, ≥98.5% (RT)
Manufacturer: Sigma Aldrich
CAS Number: 16774-21-3
Synonym(S): CAN, Ceric ammonium nitrate
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 G | 22249-100-G | In Stock | ₹ 11,691.00 |
| 500 G | 22249-500-G | In Stock | ₹ 29,130.08 |
22249 - 100 G
In Stock
Quantity
1
Base Price: ₹ 11,691.00
GST (18%): ₹ 2,104.38
Total Price: ₹ 13,795.38
grade
ACS reagentpuriss. p.a.
Quality Level
200
Assay
≥98.5% (RT)
form
powder or crystals
reaction suitability
reagent type: oxidant
anion traces
chloride (Cl-): ≤10 mg/kgphosphate (PO43-): ≤200 mg/kg
cation traces
Ca: ≤10 mg/kgCd: ≤5 mg/kgCo: ≤5 mg/kgCr: ≤5 mg/kgCu: ≤5 mg/kgFe: ≤50 mg/kgK: ≤10 mg/kgMg: ≤20 mg/kgMn: ≤5 mg/kgNa: ≤10 mg/kgNi: ≤5 mg/kgPb: ≤5 mg/kgZn: ≤5 mg/kg
SMILES string
N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
InChI
1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;
InChI key
WIBGOERAEYJBOT-UHFFFAOYSA-N
Other Options
Related Products
Description
- General description: Ammonium cerium(IV) nitrate (Cerium(IV) ammonium nitrate, CAN) is a versatile reagent for oxidative electron transfer reactions. It participates in various novel carbon-carbon bond-forming reactions involved in one-pot synthesis of dihydrofurans, tetrahydrofurans and aminotetralins.[1] Iodine/ammonium cerium(IV) nitrate has been employed in direct α-iodination of various ketones to afford the corresponding α-iodo ketones.[2] CAN has been reported as an powerful one-electron oxidant. It also participates in various carbon-heteroatom bond-forming reactions.[3]
- Application: Ammonium cerium(IV) nitrate (CAN) may be employed as catalyst for the oxidation of aliphatic or aromatic sulfides to the corresponding sulfoxides.[4] CAN in polyethylene glycol has been employed as an ecofriendly catalytic medium for the green synthesis of 2,5-disubstituted 1,3,4-oxadiazoles.[5]
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P210 - P260 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A
WGK
WGK 3
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grade: ACS reagentpuriss. p.a.
Quality Level: 200
Assay: ≥98.5% (RT)
form: powder or crystals
reaction suitability: reagent type: oxidant
anion traces: chloride (Cl-): ≤10 mg/kgphosphate (PO43-): ≤200 mg/kg
cation traces: Ca: ≤10 mg/kgCd: ≤5 mg/kgCo: ≤5 mg/kgCr: ≤5 mg/kgCu: ≤5 mg/kgFe: ≤50 mg/kgK: ≤10 mg/kgMg: ≤20 mg/kgMn: ≤5 mg/kgNa: ≤10 mg/kgNi: ≤5 mg/kgPb: ≤5 mg/kgZn: ≤5 mg/kg
SMILES string: N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
InChI: 1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;
InChI key: WIBGOERAEYJBOT-UHFFFAOYSA-N
grade: __
Quality Level: 100
Assay: 98%
form: __
reaction suitability: __
anion traces: __
cation traces: __
SMILES string: [O-][N+](=O)c1cccc(CBr)c1
InChI: 1S/C7H6BrNO2/c8-5-6-2-1-3-7(4-6)9(10)11/h1-4H,5H2
InChI key: LNWXALCHPJANMJ-UHFFFAOYSA-N
grade: __
Quality Level: 200
Assay: ≥99.9% trace metals basis
form: powder
reaction suitability: __
anion traces: __
cation traces: __
SMILES string: [Li+].[Li+].[O-]B(OB=O)OB([O-])OB=O
InChI: 1S/B4O7.2Li/c5-1-9-3(7)11-4(8)10-2-6;;/q-2;2*+1
InChI key: PSHMSSXLYVAENJ-UHFFFAOYSA-N