290998

Pentylmagnesium bromide solution

2.0 M in diethyl ether

Manufacturer: Sigma Aldrich

CAS Number: 693-25-4

Synonym(S): 1-Pentylmagnesium bromide, n-Pentylmagnesium bromide, Amylmagnesium bromide, Bromopentylmagnesium

Select a Size

Pack Size SKU Availability Price
100 ML 290998-100-ML In Stock ₹ 10,088.90
800 ML 290998-800-ML In Stock ₹ 26,445.48

290998 - 100 ML

₹ 10,088.90

In Stock

Quantity

1

Base Price: ₹ 10,088.90

GST (18%): ₹ 1,816.002

Total Price: ₹ 11,904.902

Quality Level

100

reaction suitability

reaction type: Grignard Reaction

concentration

2.0 M in diethyl ether

density

0.947 g/mL at 25 °C

SMILES string

CCCCC[Mg]Br

InChI

1S/C5H11.BrH.Mg/c1-3-5-4-2;;/h1,3-5H2,2H3;1H;/q;;+1/p-1

InChI key

ZXWGTPYWPZGZPT-UHFFFAOYSA-M

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Description

  • Application: Pentylmagnesium bromide solution is a Grignard reagent that can be used in the preparation of: Alkanes via Ni or Cu-catalyzed cross-coupling reaction with alkyl fluorides.[1]Hydroxypiperidinones via the addition-cyclization-deprotection process of aldimines.[2]It can also be used as a reagent to synthesize a key intermediate by olefin alkylation in the total synthesis of alkaloid, (+)-hyperaspine [3], and surface alkylation of H-terminated Si (111), by Si-C bond formation.[4]

SAFETY INFORMATION

Pictograms

GHS02,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H225,H260,H302,H314,H336

Precautionary Statements

P210 - P231 + P232 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

Target Organs

Central nervous system

Supplementary Hazards

EUH014,EUH019

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Quality Level:
100

reaction suitability:
reaction type: Grignard Reaction

concentration:
2.0 M in diethyl ether

density:
0.947 g/mL at 25 °C

SMILES string:
CCCCC[Mg]Br

InChI:
1S/C5H11.BrH.Mg/c1-3-5-4-2;;/h1,3-5H2,2H3;1H;/q;;+1/p-1

InChI key:
ZXWGTPYWPZGZPT-UHFFFAOYSA-M

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