324868

Potassium trimethylsilanolate

90%, technical grade

Manufacturer: Sigma Aldrich

CAS Number: 10519-96-7

Synonym(S): Trimethylsilanol potassium salt

Select a Size

Pack Size SKU Availability Price
25 G 324868-25-G In Stock ₹ 18,520.00
100 G 324868-100-G In Stock ₹ 60,430.00
1 KG 324868-1-KG In Stock ₹ 3,31,320.78

324868 - 25 G

₹ 18,520.00

In Stock

Quantity

1

Base Price: ₹ 18,520.00

GST (18%): ₹ 3,333.60

Total Price: ₹ 21,853.60

grade

technical grade

Quality Level

200

Assay

90%

mp

135-138 °C (lit.)

SMILES string

[K+].C[Si](C)(C)[O-]

InChI

1S/C3H9OSi.K/c1-5(2,3)4;/h1-3H3;/q-1;+1

InChI key

LBKJNHPKYFYCLL-UHFFFAOYSA-N

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Description

  • Application: Potassium trimethylsilanolate can be used as a reagent in the:Hydrolysis of nitriles to primary amides.[1]Conversion of esters to carboxylic acids,[2] and dialkyl phosphonates to their monoalkyl phosphonates.[3]Synthesis of E-alkenes,[4] and nitrocefin.[5]It can also be used as a coupling promoter in cross-coupling reaction of aliphatic alkynylsilanols with aryl iodides.[6]

SAFETY INFORMATION

Pictograms

GHS05

Signal Word

Danger

Hazard Statements

H314

Precautionary Statements

P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Skin Corr. 1B

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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technical grade

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135-138 °C (lit.)

SMILES string:
[K+].C[Si](C)(C)[O-]

InChI:
1S/C3H9OSi.K/c1-5(2,3)4;/h1-3H3;/q-1;+1

InChI key:
LBKJNHPKYFYCLL-UHFFFAOYSA-N

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c1ccc(cc1)N=P(c2ccccc2)(c3ccccc3)c4ccccc4

InChI:
1S/C24H20NP/c1-5-13-21(14-6-1)25-26(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24/h1-20H

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PTLOPIHJOPWUNN-UHFFFAOYSA-N

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CS(=O)(=O)c1ccc(cc1)[C@@H](O)[C@H](N)CF

InChI:
1S/C10H14FNO3S/c1-16(14,15)8-4-2-7(3-5-8)10(13)9(12)6-11/h2-5,9-10,13H,6,12H2,1H3/t9-,10-/m1/s1

InChI key:
XLSYLQDVLAXIKK-NXEZZACHSA-N