577928
Lithium bis(trimethylsilyl)amide solution
1 M in toluene
Manufacturer: Sigma Aldrich
CAS Number: 4039-32-1
Synonym(S): LiHMDS, Hexamethyldisilazane lithium salt
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 ML | 577928-100-ML | In Stock | ₹ 4,459.90 |
| 800 ML | 577928-800-ML | In Stock | ₹ 21,065.45 |
577928 - 100 ML
In Stock
Quantity
1
Base Price: ₹ 4,459.90
GST (18%): ₹ 802.782
Total Price: ₹ 5,262.682
Quality Level
200
concentration
1 M in toluene
density
0.860 g/mL at 25 °C
SMILES string
[Li]N([Si](C)(C)C)[Si](C)(C)C
InChI
1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key
YNESATAKKCNGOF-UHFFFAOYSA-N
Other Options
Related Products
Description
- General description: Lithium bis(trimethylsilyl)amide solution (LiHMDS) is generally used in organic synthesis as a non-nucleophilic strong Bronsted base.[1]
- Application: LiHMDS can be used as a reagent: In the deprotonation and nucleophilic difluoromethylation reactions.[2][3] To synthesize isoquinoline derivatives by the addition of N-iodosuccinimide (NIS) to the α-benzyl tosylmethyl isocyanides.[4] To prepare arylboronic acid pinacol esters by the reaction of aryl fluorides with bis(pinacolato)diboron via palladium-catalyzed cross-coupling reaction.[5]
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P210 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Self-heat. 1 - Skin Corr. 1B - STOT RE 2 - STOT SE 3
Target Organs
Central nervous system
Supplementary Hazards
EUH014
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Quality Level: 200
concentration: 1 M in toluene
density: 0.860 g/mL at 25 °C
SMILES string: [Li]N([Si](C)(C)C)[Si](C)(C)C
InChI: 1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key: YNESATAKKCNGOF-UHFFFAOYSA-N
Quality Level:
200
concentration:
1 M in toluene
density:
0.860 g/mL at 25 °C
SMILES string:
[Li]N([Si](C)(C)C)[Si](C)(C)C
InChI:
1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key:
YNESATAKKCNGOF-UHFFFAOYSA-N
Quality Level: 100
concentration: __
density: __
SMILES string: [H]\C(c1ccccc1OC(C)C)=[Ru](\Cl)Cl.C2CCC(CC2)P(C3CCCCC3)C4CCCCC4
InChI: 1S/C18H33P.C10H12O.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-8(2)11-10-7-5-4-6-9(10)3;;;/h16-18H,1-15H2;3-8H,1-2H3;2*1H;/q;;;;+2/p-2
InChI key: KMKCJXPECJFQPQ-UHFFFAOYSA-L
Quality Level:
100
concentration:
__
density:
__
SMILES string:
[H]\C(c1ccccc1OC(C)C)=[Ru](\Cl)Cl.C2CCC(CC2)P(C3CCCCC3)C4CCCCC4
InChI:
1S/C18H33P.C10H12O.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-8(2)11-10-7-5-4-6-9(10)3;;;/h16-18H,1-15H2;3-8H,1-2H3;2*1H;/q;;;;+2/p-2
InChI key:
KMKCJXPECJFQPQ-UHFFFAOYSA-L
Quality Level: 300
concentration: __
density: __
SMILES string: __
InChI: __
InChI key: __
Quality Level:
300
concentration:
__
density:
__
SMILES string:
__
InChI:
__
InChI key:
__
Quality Level: 100
concentration: __
density: __
SMILES string: __
InChI: 1S/C4H5N/c1-2-4-5-3-1/h1-5H
InChI key: KAESVJOAVNADME-UHFFFAOYSA-N
Quality Level:
100
concentration:
__
density:
__
SMILES string:
__
InChI:
1S/C4H5N/c1-2-4-5-3-1/h1-5H
InChI key:
KAESVJOAVNADME-UHFFFAOYSA-N