245585
Sodium bis(trimethylsilyl)amide solution
1.0 M in THF
Manufacturer: Sigma Aldrich
CAS Number: 1070-89-9
Synonym(S): Hexamethyldisilazane sodium salt solution
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 ML | 245585-100-ML | In Stock | ₹ 4,546.50 |
| 4 X 25 ML | 245585-4-X-25-ML | In Stock | ₹ 10,500.25 |
| 4 X 100 ML | 245585-4-X-100-ML | In Stock | ₹ 14,884.38 |
| 800 ML | 245585-800-ML | In Stock | ₹ 16,194.15 |
245585 - 100 ML
In Stock
Quantity
1
Base Price: ₹ 4,546.50
GST (18%): ₹ 818.37
Total Price: ₹ 5,364.87
form
liquid
Quality Level
200
concentration
1.0 M in THF
density
0.904 g/mL at 25 °C
SMILES string
C[Si](C)(C)N([Na])[Si](C)(C)C
InChI
1S/C6H18NSi2.Na/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key
WRIKHQLVHPKCJU-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences Sodium Bis(Trimethylsilyl)Amide Solution | 1070-89-9 | MFCD00009835 | 4x25ml | Sigma Aldrich Fine Chemicals Biosciences | ₹ 6,733.57 | |
 | eMolecules Sodium bis(trimethylsilyl)amide | 1070-89-9 | MFCD00009835 | 5g | eMolecules | ₹ 4,168.48 | |
 | Sigma Aldrich Fine Chemicals Biosciences Sodium bis(trimethylsilyl)amide solution 1.0 M in THF | 1070-89-9 | MFCD00009835 | 100ml | Sigma Aldrich Fine Chemicals Biosciences | ₹ 7,007.36 | |
 | Sodium bis(trimethylsilyl)amide | Sigma Aldrich | ₹ 14,256.53 | |
| | Sodium bis(trimethylsilyl)amide solution | Sigma Aldrich | ₹ 16,356.58 | |
| | Sodium bis(trimethylsilyl)amide | Sigma Aldrich | ₹ 14,256.53 | |
| | Sodium bis(trimethylsilyl)amide solution | Sigma Aldrich | ₹ 16,356.58 | |
| | Sodium bis(trimethylsilyl)amide solution | Sigma Aldrich | ₹ 3,853.70 - ₹ 18,131.88 | |
| | Sodium bis(trimethylsilyl)amide solution | Sigma Aldrich | ₹ 4,546.50 - ₹ 16,194.15 | |
 | 1070-89-9 | Sodium bis(trimethylsilyl)amide | A2B Chem | ₹ 7,015.92 - ₹ 18,053.16 |
Related Products
Description
- General description: Sodium bis(trimethylsilyl)amide solution (NaHMDS) is widely used as a strong base in organic synthesis for deprotonation reactions and base-catalyzed reactions. It is also involved in the generation of enolates, Wittig reagents and carbenes.[1][2]
- Application: NaHMDS can be used as a base: In the synthesis of N-boc-1-amino-1,3-diene derivatives from N-boc-1-amino-4-methoxy-2-alkenes via 1,4-elimination reactions.[2] To deprotonate alkyl or aryl ketones to generate enolate derivatives by hydroxylation reaction.[3] In the enantioselective synthesis of 1,2-amino alcohols by the reaction between various nitroalkanes and aldehydes via nitroaldol reaction promoted by bimetallic heterogeneous catalyst.[4]
- Packaging: The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
- Legal Information: Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P202 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
EUH014,EUH019
WGK
WGK 2
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
form: liquid
Quality Level: 200
concentration: 1.0 M in THF
density: 0.904 g/mL at 25 °C
SMILES string: C[Si](C)(C)N([Na])[Si](C)(C)C
InChI: 1S/C6H18NSi2.Na/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key: WRIKHQLVHPKCJU-UHFFFAOYSA-N
form:
liquid
Quality Level:
200
concentration:
1.0 M in THF
density:
0.904 g/mL at 25 °C
SMILES string:
C[Si](C)(C)N([Na])[Si](C)(C)C
InChI:
1S/C6H18NSi2.Na/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key:
WRIKHQLVHPKCJU-UHFFFAOYSA-N
form: liquid
Quality Level: __
concentration: __
density: 0.917 g/mL at 25 °C (lit.)
SMILES string: COC(=O)CCN(C)C
InChI: 1S/C6H13NO2/c1-7(2)5-4-6(8)9-3/h4-5H2,1-3H3
InChI key: VSFJOMFYABROHQ-UHFFFAOYSA-N
form:
liquid
Quality Level:
__
concentration:
__
density:
0.917 g/mL at 25 °C (lit.)
SMILES string:
COC(=O)CCN(C)C
InChI:
1S/C6H13NO2/c1-7(2)5-4-6(8)9-3/h4-5H2,1-3H3
InChI key:
VSFJOMFYABROHQ-UHFFFAOYSA-N
form: solid
Quality Level: 100
concentration: __
density: __
SMILES string: Clc1ccc(cc1Cl)N=C=O
InChI: 1S/C7H3Cl2NO/c8-6-2-1-5(10-4-11)3-7(6)9/h1-3H
InChI key: MFUVCHZWGSJKEQ-UHFFFAOYSA-N
form:
solid
Quality Level:
100
concentration:
__
density:
__
SMILES string:
Clc1ccc(cc1Cl)N=C=O
InChI:
1S/C7H3Cl2NO/c8-6-2-1-5(10-4-11)3-7(6)9/h1-3H
InChI key:
MFUVCHZWGSJKEQ-UHFFFAOYSA-N
form: __
Quality Level: 200
concentration: __
density: __
SMILES string: [O-][N+](=O)c1ccc(cc1)C(=O)CBr
InChI: 1S/C8H6BrNO3/c9-5-8(11)6-1-3-7(4-2-6)10(12)13/h1-4H,5H2
InChI key: MBUPVGIGAMCMBT-UHFFFAOYSA-N
form:
__
Quality Level:
200
concentration:
__
density:
__
SMILES string:
[O-][N+](=O)c1ccc(cc1)C(=O)CBr
InChI:
1S/C8H6BrNO3/c9-5-8(11)6-1-3-7(4-2-6)10(12)13/h1-4H,5H2
InChI key:
MBUPVGIGAMCMBT-UHFFFAOYSA-N