715468

Barium tert-butoxide

85%

Manufacturer: Sigma Aldrich

CAS Number: 24363-36-8

Synonym(S): Barium di-t-butoxide

Select a Size

Pack Size SKU Availability Price
1 G 715468-1-G In Stock ₹ 6,884.70

715468 - 1 G

₹ 6,884.70

In Stock

Quantity

1

Base Price: ₹ 6,884.70

GST (18%): ₹ 1,239.246

Total Price: ₹ 8,123.946

Quality Level

100

Assay

85%

form

powder

mp

>200 °C

storage temp.

2-8°C

SMILES string

CC(C)(C)O[Ba]OC(C)(C)C

InChI

1S/2C4H9O.Ba/c2*1-4(2,3)5;/h2*1-3H3;/q2*-1;+2

InChI key

SLPLCLDJTNLWPW-UHFFFAOYSA-N

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Description

  • General description: Barium tert-butoxide is a Brønsted base catalyst that can be used as a precursor of various barium catalysts like barium aryloxide. It can also be used in the preparation of barium diphenylmethanide, applicable in the organometallic chemistry.[1]
  • Application: Barium tert-butoxide can be used:As a catalyst along with various phenolic ligands in the aldol reactions of amides with aldehydes and ketones.[2]To prepare yttrium and copper metal complexes by reacting with Y(thd)3 and Cu(thd)2, where “thd” is 2,2,6,6-tetramethylheptane-3,5-dione.[3]As an initiator along with an alkyl lithium in the butadiene copolymerization reaction.[4]In the iridium catalyzed allylic alkylation of non-stabilized enolates.[5]

SAFETY INFORMATION

Pictograms

GHS02,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H228,H314,H335

Precautionary Statements

P210 - P240 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Flam. Sol. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH014

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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powder

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>200 °C

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SMILES string:
CC(C)(C)O[Ba]OC(C)(C)C

InChI:
1S/2C4H9O.Ba/c2*1-4(2,3)5;/h2*1-3H3;/q2*-1;+2

InChI key:
SLPLCLDJTNLWPW-UHFFFAOYSA-N

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