79267

Trimethylphenylammonium hydroxide solution

~25% in H2O (1.68 M)

Manufacturer: Sigma Aldrich

CAS Number: 1899-02-1

Synonym(S): Phenyltrimethylammonium hydroxide, TMAH

Select a Size

Pack Size SKU Availability Price
100 ML 79267-100-ML In Stock ₹ 27,246.53

79267 - 100 ML

₹ 27,246.53

In Stock

Quantity

1

Base Price: ₹ 27,246.53

GST (18%): ₹ 4,904.375

Total Price: ₹ 32,150.905

form

liquid

Quality Level

100

concentration

~25% in H2O (1.68 M)

refractive index

n20/D 1.395

SMILES string

[OH-].C[N+](C)(C)c1ccccc1

InChI

1S/C9H14N.H2O/c1-10(2,3)9-7-5-4-6-8-9;/h4-8H,1-3H3;1H2/q+1;/p-1

InChI key

HADKRTWCOYPCPH-UHFFFAOYSA-M

Other Options

Image Product Name Manufacturer Price Range
NC1872140
High Purity Products TMAH 25% | 1899-02-1 | MFCD00041899 | 5 gal pail
High Purity Products ₹ 35,079.60
NC1289581
Aqua Solutions TMAH 0.1 N in MEOH | 1899-02-1 | MFCD00041899 | 1 L
Aqua Solutions ₹ 23,143.98
79266
Trimethylphenylammonium hydroxide solution
Supelco ₹ 13,141.55 - ₹ 29,086.78
79267
Trimethylphenylammonium hydroxide solution
Sigma Aldrich ₹ 27,246.53
CS-W010937
Phenyltrimethylammonium hydroxide
ChemScene ₹ 6,074.76 - ₹ 22,587.84
AB11405
1899-02-1 | Benzenaminium, N,N,N-trimethyl-, hydroxide (1:1)
A2B Chem ₹ 2,224.56 - ₹ 14,117.40

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Description

  • General description: Trimethylphenylammonium hydroxide solution (TMPAH) is a quaternary ammonium compound that is commonly used as a strong base in organic synthesis. It is also used as a deprotecting agent for the removal of t-butoxycarbonyl (Boc) groups from amino acids or peptides and benzyl protecting groups from alcohols or amines.
  • Application: Trimethylphenylammonium hydroxide solution can be used to initiate the polymerization of the monomer 1,8-dihydroxymethyl-1,3,5,7-octatetrayne (DHOT) for the preparation of polymer nanospheres. It is also used as a base in the synthesis of alkyl 3-nitroacrylates via aldol reaction with nitroacetaldehyde or nitroacetone.

SAFETY INFORMATION

Pictograms

GHS05

Signal Word

Danger

Hazard Statements

H314

Precautionary Statements

P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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79267

~25% in H2O (1.68 M)...


form:
liquid

Quality Level:
100

concentration:
~25% in H2O (1.68 M)

refractive index:
n20/D 1.395

SMILES string:
[OH-].C[N+](C)(C)c1ccccc1

InChI:
1S/C9H14N.H2O/c1-10(2,3)9-7-5-4-6-8-9;/h4-8H,1-3H3;1H2/q+1;/p-1

InChI key:
HADKRTWCOYPCPH-UHFFFAOYSA-M

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Cc1ccccc1N=Nc2c(O)ccc3ccccc23

InChI:
1S/C17H14N2O/c1-12-6-2-5-9-15(12)18-19-17-14-8-4-3-7-13(14)10-11-16(17)20/h2-11,20H,1H3

InChI key:
BQFCCCIRTOLPEF-UHFFFAOYSA-N

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CN(C)CCNS(=O)(=O)c1ccc(NCCN)c2nonc12

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1S/C12H20N6O3S/c1-18(2)8-7-15-22(19,20)10-4-3-9(14-6-5-13)11-12(10)17-21-16-11/h3-4,14-15H,5-8,13H2,1-2H3

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refractive index:
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SMILES string:
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InChI:
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InChI key:
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