345571
1,5,7-Triazabicyclo[4.4.0]dec-5-ene
98%
Manufacturer: Sigma Aldrich
CAS Number: 5807-14-7
Synonym(S): 1,3,4,6,7,8-Hexahydro-2H-pyrimido[1,2-a]pyrimidine, Hhpp, TBD
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 5 G | 345571-5-G | In Stock | ₹ 7,081.80 |
345571 - 5 G
In Stock
Quantity
1
Base Price: ₹ 7,081.80
GST (18%): ₹ 1,274.724
Total Price: ₹ 8,356.524
Quality Level
200
Assay
98%
form
crystals
mp
125-130 °C (lit.)
solubility
acetonitrile: solubleethanol: solubleorganic solvents: solublewater: soluble
SMILES string
C1CNC2=NCCCN2C1
InChI
1S/C7H13N3/c1-3-8-7-9-4-2-6-10(7)5-1/h1-6H2,(H,8,9)
InChI key
FVKFHMNJTHKMRX-UHFFFAOYSA-N
Related Products
Description
- General description: 1,5,7-Triazabicyclo[4.4.0]dec-5-ene, a bicyclic guanidine base, has been found to be an excellent catalyst for Michael and Michael-type reactions.[1] It forms 1:1 complex with lasalocid acid and crystal structure of the complex has been studied by X-ray diffraction, FT-IR spectroscopy and 1H NMR.[2]
- Application: 1,5,7-Triazabicyclo[4.4.0]dec-5-ene may be used as organocatalyst for aminolysis of esters.[3] It may be used as catalyst for direct addition of P(O)-H bonds (dialkyl phosphites and diphenyl phosphonite) across various activated alkenes.[4] Polymer supported 1,5,7-triazabicyclo[4.4.0]dec-5-ene (PTBD) was used as a base and a reagent scavenger for the synthesis of aryl ethers from phenols and alkyl or aryl halides.[5]
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
Hazard Classifications
Skin Corr. 1B
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 200
Assay: 98%
form: crystals
mp: 125-130 °C (lit.)
solubility: acetonitrile: solubleethanol: solubleorganic solvents: solublewater: soluble
SMILES string: C1CNC2=NCCCN2C1
InChI: 1S/C7H13N3/c1-3-8-7-9-4-2-6-10(7)5-1/h1-6H2,(H,8,9)
InChI key: FVKFHMNJTHKMRX-UHFFFAOYSA-N
Quality Level:
200
Assay:
98%
form:
crystals
mp:
125-130 °C (lit.)
solubility:
acetonitrile: solubleethanol: solubleorganic solvents: solublewater: soluble
SMILES string:
C1CNC2=NCCCN2C1
InChI:
1S/C7H13N3/c1-3-8-7-9-4-2-6-10(7)5-1/h1-6H2,(H,8,9)
InChI key:
FVKFHMNJTHKMRX-UHFFFAOYSA-N
Quality Level: 100
Assay: 98%
form: solid
mp: 33-37 °C (lit.)
solubility: __
SMILES string: Oc1c(F)ccc(F)c1F
InChI: 1S/C6H3F3O/c7-3-1-2-4(8)6(10)5(3)9/h1-2,10H
InChI key: QSFGUSFDWCVXNR-UHFFFAOYSA-N
Quality Level:
100
Assay:
98%
form:
solid
mp:
33-37 °C (lit.)
solubility:
__
SMILES string:
Oc1c(F)ccc(F)c1F
InChI:
1S/C6H3F3O/c7-3-1-2-4(8)6(10)5(3)9/h1-2,10H
InChI key:
QSFGUSFDWCVXNR-UHFFFAOYSA-N
Quality Level: 100
Assay: 98%
form: __
mp: __
solubility: __
SMILES string: Nc1c(F)cccc1C(F)(F)F
InChI: 1S/C7H5F4N/c8-5-3-1-2-4(6(5)12)7(9,10)11/h1-3H,12H2
InChI key: CQSFHEFEKDRLKE-UHFFFAOYSA-N
Quality Level:
100
Assay:
98%
form:
__
mp:
__
solubility:
__
SMILES string:
Nc1c(F)cccc1C(F)(F)F
InChI:
1S/C7H5F4N/c8-5-3-1-2-4(6(5)12)7(9,10)11/h1-3H,12H2
InChI key:
CQSFHEFEKDRLKE-UHFFFAOYSA-N
Quality Level: 100
Assay: 97%
form: liquid
mp: __
solubility: __
SMILES string: CC(=C)CBr
InChI: 1S/C4H7Br/c1-4(2)3-5/h1,3H2,2H3
InChI key: __
Quality Level:
100
Assay:
97%
form:
liquid
mp:
__
solubility:
__
SMILES string:
CC(=C)CBr
InChI:
1S/C4H7Br/c1-4(2)3-5/h1,3H2,2H3
InChI key:
__