DavePhos
97%
Manufacturer: Sigma Aldrich
CAS Number: 213697-53-1
Synonym(S): 2-Dicyclohexylphosphino-2′-(N,N-dimethylamino)biphenyl
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 G | 638021-1-G | In Stock | ₹ 17,103.50 |
| 5 G | 638021-5-G | In Stock | ₹ 43,657.23 |
| 25 G | 638021-25-G | In Stock | ₹ 1,63,879.68 |
| 100 G | 638021-100-G | In Stock | ₹ 4,32,664.43 |
638021 - 1 G
In Stock
Quantity
1
Base Price: ₹ 17,103.50
GST (18%): ₹ 3,078.63
Total Price: ₹ 20,182.13
Quality Level
200
Assay
97%
reaction suitability
reaction type: Cross Couplingsreagent type: ligandreaction type: Arylationsreagent type: ligandreaction type: Buchwald-Hartwig Cross Coupling Reactionreagent type: ligandreaction type: Hydroaminationsreagent type: ligandreaction type: Kumada Couplingreagent type: ligandreaction type: Negishi Couplingreagent type: ligandreaction type: Suzuki-Miyaura Coupling
mp
121-124 °C (lit.)
functional group
phosphine
SMILES string
CN(C)c1ccccc1-c2ccccc2P(C3CCCCC3)C4CCCCC4
InChI
1S/C26H36NP/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22/h9-12,17-22H,3-8,13-16H2,1-2H3
InChI key
ZEMZPXWZVTUONV-UHFFFAOYSA-N
Other Options
Related Products
Description
- Application: DavePhos may be used as a ligand in the following reactions:Palladium catalyzed sp3 arylation of 2-substituted-N-iminopyridinium ylides with different aryl chlorides to yield functionalized pyridines.[1]Preparation of functionalized benzylic sulfones via palladium-catalyzed Negishi cross-coupling between alkyl sulfones and aryl halides.[2]C-C Coupling of 3-haloquinolines with aryl sulfinates via palladium-catalyzed desulfitative arylation to form the corresponding biaryl compounds.[3]
- Legal Information: Usage subject to US Patents 6307087 and 6395916.
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 200
Assay: 97%
reaction suitability: reaction type: Cross Couplingsreagent type: ligandreaction type: Arylationsreagent type: ligandreaction type: Buchwald-Hartwig Cross Coupling Reactionreagent type: ligandreaction type: Hydroaminationsreagent type: ligandreaction type: Kumada Couplingreagent type: ligandreaction type: Negishi Couplingreagent type: ligandreaction type: Suzuki-Miyaura Coupling
mp: 121-124 °C (lit.)
functional group: phosphine
SMILES string: CN(C)c1ccccc1-c2ccccc2P(C3CCCCC3)C4CCCCC4
InChI: 1S/C26H36NP/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22/h9-12,17-22H,3-8,13-16H2,1-2H3
InChI key: ZEMZPXWZVTUONV-UHFFFAOYSA-N
Quality Level: 300
Assay: 98%
reaction suitability: reaction type: Cross Couplingsreagent type: ligandreaction type: Buchwald-Hartwig Cross Coupling Reactionreagent type: ligandreaction type: C-C Bond Formationreagent type: ligandreaction type: Heck Reactionreagent type: ligandreaction type: Hiyama Couplingreagent type: ligandreaction type: Negishi Couplingreagent type: ligandreaction type: Sonogashira Couplingreagent type: ligandreaction type: Stille Couplingreagent type: ligandreaction type: Suzuki-Miyaura Coupling
mp: 187-190 °C (lit.)
functional group: phosphine
SMILES string: CC(C)C1=CC(C(C)C)=CC(C(C)C)=C1C2=C(P(C3CCCCC3)C4CCCCC4)C=CC=C2
InChI: __
InChI key: __
Quality Level: 300
Assay: 98%
reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligandreaction type: Buchwald-Hartwig Cross Coupling Reactionreagent type: ligandreaction type: Heck Reactionreagent type: ligandreaction type: Kumada Couplingreagent type: ligandreaction type: Negishi Couplingreagent type: ligandreaction type: Suzuki-Miyaura Coupling
mp: 164-166 °C (lit.)
functional group: phosphine
SMILES string: COc1cccc(OC)c1-c2ccccc2P(C3CCCCC3)C4CCCCC4
InChI: __
InChI key: __
