158496
Proton-sponge®
99%
Manufacturer: Sigma Aldrich
CAS Number: 20734-58-1
Synonym(S): 1,8-Bis(dimethylamino)naphthalene, N,N,N′,N′-Tetramethyl-1,8-naphthalenediamine
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 10 G | 158496-10-G | In Stock | ₹ 2,901.10 |
| 50 G | 158496-50-G | In Stock | ₹ 10,262.10 |
158496 - 10 G
In Stock
Quantity
1
Base Price: ₹ 2,901.10
GST (18%): ₹ 522.198
Total Price: ₹ 3,423.298
Quality Level
200
Assay
99%
form
solid
mp
49-51 °C (lit.)
solubility
chloroform: soluble 50 mg/mL, clear (faint yellow to dark yellow to dark red)
SMILES string
CN(C)c1cccc2cccc(N(C)C)c12
InChI
1S/C14H18N2/c1-15(2)12-9-5-7-11-8-6-10-13(14(11)12)16(3)4/h5-10H,1-4H3
InChI key
GJFNRSDCSTVPCJ-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences Proton-sponge(R) 99% | 20734-58-1 | MFCD00003920 | 50G | Sigma Aldrich Fine Chemicals Biosciences | ₹ 16,875.00 | |
| | Sigma Aldrich Fine Chemicals Biosciences N,N,N',N'-Tetramethyl-1,8-naphthalenediamine purum, >=99.0% (NT) | 20734-58-1 | MFCD00003920 | 50G | Sigma Aldrich Fine Chemicals Biosciences | ₹ 21,486.68 | |
 | Proton-sponge® | Sigma Aldrich | ₹ 2,901.10 - ₹ 10,262.10 | |
| | N,N,N′,N′-Tetramethyl-1,8-naphthalenediamine | Sigma Aldrich | ₹ 5,260.95 - ₹ 17,937.03 | |
 | 1,8-Naphthalenediamine, N1,N1,N8,N8-tetramethyl- | Aaron Chemicals LLC | ₹ 256.68 - ₹ 21,988.92 | |
 | Proton sponge | ChemScene | ₹ 770.04 - ₹ 32,427.24 | |
 | 20734-58-1 | 1,8-Bis(dimethylamino)naphthalene | A2B Chem | ₹ 427.80 - ₹ 4,876.92 |
Related Products
Description
- General description: Proton-sponge is a nucleophilic base used in alkoxycarbonylation, dehydrofluorination, arylation, and intramolecular cyclization reactions.[1]Proton-sponge is also referred to as 1,8-dimethylamino naphthalene.[2] It is very strong base with weak nucleophilic character due to steric effects.[3] It also participates in the reactions between arachno-6,9-C2B8H14 and selected acyl chlorides.[2] It has been tested as an effective H+ scavenger.[4]
- Application: Proton-sponge can be used in the synthesis of C-substituted t-BuNH-8,9-R,R′-nido-7,8,9-C3B8H9 (R,R′ = H,H; MeH; Me,Me; Ph,H and Ph,Ph) tricarbollide compounds.[5] It was also used in the preparation of saturated fluoroalkyl(hydrido) complexes of Iridium.[6]
- Legal Information: Proton-sponge is a registered trademark of Merck KGaA, Darmstadt, Germany
SAFETY INFORMATION
Pictograms
Signal Word
Warning
Hazard Statements
Precautionary Statements
P261 - P264 - P271 - P301 + P312 - P302 + P352 - P305 + P351 + P338
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 200
Assay: 99%
form: solid
mp: 49-51 °C (lit.)
solubility: chloroform: soluble 50 mg/mL, clear (faint yellow to dark yellow to dark red)
SMILES string: CN(C)c1cccc2cccc(N(C)C)c12
InChI: 1S/C14H18N2/c1-15(2)12-9-5-7-11-8-6-10-13(14(11)12)16(3)4/h5-10H,1-4H3
InChI key: GJFNRSDCSTVPCJ-UHFFFAOYSA-N
Quality Level:
200
Assay:
99%
form:
solid
mp:
49-51 °C (lit.)
solubility:
chloroform: soluble 50 mg/mL, clear (faint yellow to dark yellow to dark red)
SMILES string:
CN(C)c1cccc2cccc(N(C)C)c12
InChI:
1S/C14H18N2/c1-15(2)12-9-5-7-11-8-6-10-13(14(11)12)16(3)4/h5-10H,1-4H3
InChI key:
GJFNRSDCSTVPCJ-UHFFFAOYSA-N
Quality Level: __
Assay: __
form: __
mp: 189-191 °C (lit.)
solubility: __
SMILES string: NC(=O)c1cnccn1
InChI: 1S/C5H5N3O/c6-5(9)4-3-7-1-2-8-4/h1-3H,(H2,6,9)
InChI key: IPEHBUMCGVEMRF-UHFFFAOYSA-N
Quality Level:
__
Assay:
__
form:
__
mp:
189-191 °C (lit.)
solubility:
__
SMILES string:
NC(=O)c1cnccn1
InChI:
1S/C5H5N3O/c6-5(9)4-3-7-1-2-8-4/h1-3H,(H2,6,9)
InChI key:
IPEHBUMCGVEMRF-UHFFFAOYSA-N
Quality Level: 100
Assay: 98%
form: solid
mp: 98-100 °C (lit.)
solubility: ethanol: soluble 10%, clear, colorless
SMILES string: OC(=O)COc1ccccc1
InChI: 1S/C8H8O3/c9-8(10)6-11-7-4-2-1-3-5-7/h1-5H,6H2,(H,9,10)
InChI key: LCPDWSOZIOUXRV-UHFFFAOYSA-N
Quality Level:
100
Assay:
98%
form:
solid
mp:
98-100 °C (lit.)
solubility:
ethanol: soluble 10%, clear, colorless
SMILES string:
OC(=O)COc1ccccc1
InChI:
1S/C8H8O3/c9-8(10)6-11-7-4-2-1-3-5-7/h1-5H,6H2,(H,9,10)
InChI key:
LCPDWSOZIOUXRV-UHFFFAOYSA-N
Quality Level: 200
Assay: 98%
form: liquid
mp: __
solubility: __
SMILES string: OS(=O)(=O)C(F)(F)F
InChI: __
InChI key: __
Quality Level:
200
Assay:
98%
form:
liquid
mp:
__
solubility:
__
SMILES string:
OS(=O)(=O)C(F)(F)F
InChI:
__
InChI key:
__