Dimethyl chloromalonate
94%
Manufacturer: Sigma Aldrich
CAS Number: 28868-76-0
Synonym(S): 1,3-Dimethyl 2-chloropropanedioate, 2-Chloro-malonic acid dimethyl ester, Chloropropanedioic acid dimethyl ester, Dimethyl α-chloromalonate, Dimethyl 2-chloromalonate, Dimethyl 2-chloropropanedioate
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 25 G | 374539-25-G | In Stock | ₹ 14,722.00 |
| 100 G | 374539-100-G | In Stock | ₹ 53,951.80 |
374539 - 25 G
In Stock
Quantity
1
Base Price: ₹ 14,722.00
GST (18%): ₹ 2,649.96
Total Price: ₹ 17,371.96
Quality Level
200
Assay
94%
form
liquid
impurities
4-5% dimethyl dichloromalonate
refractive index
n20/D 1.437 (lit.)
bp
105-106 °C/19 mmHg (lit.)
density
1.305 g/mL at 25 °C (lit.)
SMILES string
COC(=O)C(Cl)C(=O)OC
InChI
1S/C5H7ClO4/c1-9-4(7)3(6)5(8)10-2/h3H,1-2H3
InChI key
LNBQBURECUEBKZ-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | eMolecules Ambeed / Dimethyl 2-chloromalonate / 5g / 490545364 / A259357 / / 28868-76-0 / MFCD00042837 / 166.560 / C5H7ClO4 | eMolecules | ₹ 2,678.88 | |
 | Propanedioic acid, 2-chloro-, 1,3-dimethyl ester | Aaron Chemicals LLC | -- | |
 | Dimethyl 2-chloromalonate | ChemScene | ₹ 3,764.64 - ₹ 13,604.04 |
Related Products
Description
- General description: Dimethyl chloromalonate (dimethyl 2-chloromalonate) is a dialkyl 2-substituted malonate.[1] Carbanions of dimethyl chloromalonate are reported to react with naphthoquinone derivatives, via vicarious nucleophilic substitution or oxidative nucleophilic substitution of hydrogen processes.[2] Dimethyl chloromalonate is reported to react with hydroquinone and monosubstituted hydroquinones to afford 2-oxido-benzo[b]furan derivatives.[3] Synthesis of dimethyl 2-chloromalonate, via chlorination of dimethyl malonate has been reported.[1]
- Application: Dimethyl chloromalonate is suitable for use in the synthesis of 4,5,6-trichloropyrimidine.[4] It may be used in the stereoselective synthesis of highly functionalized nitrocyclopropanes.[5] It may be used in one-pot synthesis of tetra-alkoxycarbonylallylidenetriphenylphosphoranes.[6]
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405
Hazard Classifications
Skin Corr. 1B
WGK
WGK 3
Flash Point(F)
224.6 °F
Flash Point(C)
107 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
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Quality Level: 200
Assay: 94%
form: liquid
impurities: 4-5% dimethyl dichloromalonate
refractive index: n20/D 1.437 (lit.)
bp: 105-106 °C/19 mmHg (lit.)
density: 1.305 g/mL at 25 °C (lit.)
SMILES string: COC(=O)C(Cl)C(=O)OC
InChI: 1S/C5H7ClO4/c1-9-4(7)3(6)5(8)10-2/h3H,1-2H3
InChI key: LNBQBURECUEBKZ-UHFFFAOYSA-N
Quality Level: 200
Assay: 96%
form: liquid
impurities: __
refractive index: n20/D 1.420 (lit.)
bp: 116 °C/9 mmHg (lit.)
density: 1.108 g/mL at 25 °C (lit.)
SMILES string: COCCC(O)=O
InChI: 1S/C4H8O3/c1-7-3-2-4(5)6/h2-3H2,1H3,(H,5,6)
InChI key: YSIKHBWUBSFBRZ-UHFFFAOYSA-N
Quality Level: __
Assay: 97%
form: liquid
impurities: __
refractive index: n20/D 1.516 (lit.)
bp: 125-128 °C/0.14 mmHg (lit.)
density: 1.125 g/mL at 25 °C (lit.)
SMILES string: CCCC[Sn](CCCC)(CCCC)c1ccccc1
InChI: 1S/C6H5.3C4H9.Sn/c1-2-4-6-5-3-1;3*1-3-4-2;/h1-5H;3*1,3-4H2,2H3;
InChI key: SYUVAXDZVWPKSI-UHFFFAOYSA-N
