376159

(Trimethylsilyl)methyl isocyanide

97%

Manufacturer: Sigma Aldrich

CAS Number: 30718-17-3

Synonym(S): (Isocyanomethyl)trimethylsilane

Select a Size

Pack Size SKU Availability Price
500 MG 376159-500-MG In Stock ₹ 16,627.20

376159 - 500 MG

₹ 16,627.20

In Stock

Quantity

1

Base Price: ₹ 16,627.20

GST (18%): ₹ 2,992.896

Total Price: ₹ 19,620.096

Quality Level

200

Assay

97%

form

liquid

refractive index

n20/D 1.416 (lit.)

bp

52-53 °C/35 mmHg (lit.)

density

0.803 g/mL at 25 °C (lit.)

storage temp.

−20°C

SMILES string

C[Si](C)(C)C[N+]#[C-]

InChI

1S/C5H11NSi/c1-6-5-7(2,3)4/h5H2,2-4H3

InChI key

OLSTVZKPVGMQKB-UHFFFAOYSA-N

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Description

  • General description: Synthesis of (trimethylsilyl)methyl isocyanide and its reaction with protic nucleophiles has been reported.[1] An improved preparation of (trimethylsilyl)methyl isocyanide is reported.[2] Reaction of (trimethylsilyl)methyl isocyanide with (η2-formaldehyde)zirconocene complex is reported to yield insertion products.[3]
  • Application: (Trimethylsilyl)methyl isocyanide may be used in the preparation of isocyanomethylenetriphenylphosphorane.[4]
  • Packaging: Bottomless glass bottle. Contents are inside inserted fused cone.

SAFETY INFORMATION

Pictograms

GHS02,GHS06

Signal Word

Danger

Hazard Statements

H225,H301 + H311 + H331

Precautionary Statements

P210 - P233 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P311

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

376159

97%...


Quality Level:
200

Assay:
97%

form:
liquid

refractive index:
n20/D 1.416 (lit.)

bp:
52-53 °C/35 mmHg (lit.)

density:
0.803 g/mL at 25 °C (lit.)

storage temp.:
−20°C

SMILES string:
C[Si](C)(C)C[N+]#[C-]

InChI:
1S/C5H11NSi/c1-6-5-7(2,3)4/h5H2,2-4H3

InChI key:
OLSTVZKPVGMQKB-UHFFFAOYSA-N

Img

Sigma Aldrich

376213

technical grade...


Quality Level:
100

Assay:
__

form:
liquid

refractive index:
n20/D 1.439 (lit.)

bp:
__

density:
0.883 g/mL at 25 °C (lit.)

storage temp.:
__

SMILES string:
CCCCCCCCCCCCCCCCCC[Si](OC)(OC)OC

InChI:
1S/C21H46O3Si/c1-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19-20-21-25(22-2,23-3)24-4/h5-21H2,1-4H3

InChI key:
SLYCYWCVSGPDFR-UHFFFAOYSA-N

Img

Sigma Aldrich

376221

96%...


Quality Level:
100

Assay:
96%

form:
liquid

refractive index:
n20/D 1.416 (lit.)

bp:
__

density:
0.907 g/mL at 25 °C (lit.)

storage temp.:
__

SMILES string:
CCCCCCCC[Si](OC)(OC)OC

InChI:
1S/C11H26O3Si/c1-5-6-7-8-9-10-11-15(12-2,13-3)14-4/h5-11H2,1-4H3

InChI key:
NMEPHPOFYLLFTK-UHFFFAOYSA-N

Img

Sigma Aldrich

376353

97%...


Quality Level:
200

Assay:
97%

form:
__

refractive index:
__

bp:
__

density:
__

storage temp.:
__

SMILES string:
COC(=O)C(NC(=O)OCc1ccccc1)P(=O)(OC)OC

InChI:
1S/C13H18NO7P/c1-18-12(15)11(22(17,19-2)20-3)14-13(16)21-9-10-7-5-4-6-8-10/h4-8,11H,9H2,1-3H3,(H,14,16)

InChI key:
GSYSFVSGPABNNL-UHFFFAOYSA-N