376264

Trimethyl(propargyl)silane

contains 500 ppm BHT as stabilizer

Manufacturer: Sigma Aldrich

CAS Number: 13361-64-3

Synonym(S): 2-Propynyl-trimethylsilane, 3-(Trimethylsilyl)propyne

Select a Size

Pack Size SKU Availability Price
1 G 376264-1-G In Stock ₹ 13,580.00

376264 - 1 G

₹ 13,580.00

In Stock

Quantity

1

Base Price: ₹ 13,580.00

GST (18%): ₹ 2,444.40

Total Price: ₹ 16,024.40

form

liquid

Quality Level

200

contains

500 ppm BHT as stabilizer≤20% trimethylallenylsilane (in equilibrium)

refractive index

n20/D 1.413 (lit.)

bp

91-93 °C (lit.)

density

0.753 g/mL at 25 °C (lit.)

storage temp.

−20°C

SMILES string

C[Si](C)(C)CC#C

InChI

1S/C6H12Si/c1-5-6-7(2,3)4/h1H,6H2,2-4H3

InChI key

ULYLMHUHFUQKOE-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-244-7023
eMolecules​ AstaTech / PROPARGYLTRIMETHYLSILANE / 1g / 290668426 / I10158 / 88.000 / 13361-64-3 / MFCD00042922 / 112.247 / C6H12Si
eMolecules​ ₹ 8,060.61
AB51371
13361-64-3 | Propargyltrimethylsilane, tech grade
A2B Chem ₹ 6,331.44 - ₹ 1,71,975.60

Description

  • General description: Trimethyl(propargyl)silane (2-Propynyl-trimethylsilane) is a clear colorless liquid and contains 500ppm of butylated hydroxytoluene (BHT) as stabilizer. It undergoes GaCl3-catalyzed dehydrogenation reaction with aldimines to afford 4-methylquinoline.[1]
  • Application: Trimethyl(propargyl)silane is suitable for use in the synthesis of diverse end-functionalized (ω-carboxyl, ω-hydroxy, ω-methyl-vinyl, ω-trimethylsilane, and ω-glycidyl-ether) via ′′click′′ reaction.[2] It may be used in the synthesis of γ-allenyl-GABA (γ-aminobutyric acid), via Lewis acid mediated reaction with ω-ethoxy lactams.[3]
  • Packaging: Bottomless glass bottle. Contents are inside inserted fused cone.

SAFETY INFORMATION

Pictograms

GHS02,GHS07

Signal Word

Danger

Hazard Statements

H225,H315,H319,H335

Precautionary Statements

P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

23.0 °F

Flash Point(C)

-5 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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contains 500 ppm BHT as stabilizer...


form:
liquid

Quality Level:
200

contains:
500 ppm BHT as stabilizer≤20% trimethylallenylsilane (in equilibrium)

refractive index:
n20/D 1.413 (lit.)

bp:
91-93 °C (lit.)

density:
0.753 g/mL at 25 °C (lit.)

storage temp.:
−20°C

SMILES string:
C[Si](C)(C)CC#C

InChI:
1S/C6H12Si/c1-5-6-7(2,3)4/h1H,6H2,2-4H3

InChI key:
ULYLMHUHFUQKOE-UHFFFAOYSA-N

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1S/C6H14OSi/c1-8(2,3)6-4-5-7/h4-5,7H,6H2,1-3H3/b5-4+

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CC1(C)[C@@H](CC[C@]1(C)C(O)=O)C(O)=O

InChI:
1S/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)/t6-,10+/m0/s1

InChI key:
LSPHULWDVZXLIL-QUBYGPBYSA-N