377953

2-Chloro-1,3,2-dioxaphospholane 2-oxide

Manufacturer: Sigma Aldrich

CAS Number: 6609-64-9

Synonym(S): 2-Chloro-2-oxo-1,3,2-dioxaphospholane, Ethylene glycol chlorophosphate

Select a Size

Pack Size SKU Availability Price
5 G 377953-5-G In Stock ₹ 13,325.58

377953 - 5 G

₹ 13,325.58

In Stock

Quantity

1

Base Price: ₹ 13,325.58

GST (18%): ₹ 2,398.604

Total Price: ₹ 15,724.184

form

liquid

Quality Level

200

impurities

<10% 2-Chloro-1,3,2-dioxaphospholane

refractive index

n20/D 1.45 (lit.)

bp

89-91 °C/0.8 mmHg (lit.)

mp

12-14 °C (neat) (lit.)

density

1.55 g/mL at 25 °C (lit.)

storage temp.

−20°C

SMILES string

ClP1(=O)OCCO1

InChI

1S/C2H4ClO3P/c3-7(4)5-1-2-6-7/h1-2H2

Other Options

Image Product Name Manufacturer Price Range
AR0033W6
2-Chloro-1,3,2-dioxaphospholane-2-oxide
Aaron Chemicals LLC --
AB43914
6609-64-9 | 2-Chloro-1,3,2-dioxaphospholane-2-oxide
A2B Chem --

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Description

  • General description: 2-Chloro-1,3,2-dioxaphospholane 2-oxide (COP) is a cyclic chlorophosphate reagent[1] that can be prepared from 2-chloro-1,3,2-dioxaphospholane by reacting with molecular oxygen [2].2-Chloro-1,3,2-dioxaphospholane 2-oxide is used in esterification reactions for cyclic phosphate synthesis, also reacts with phenyl grignard reagents. [3] [4]
  • Application: 2-Chloro-1,3,2-dioxaphospholane 2-oxide may be used in the synthesis of: 2-methacryloyloxyethylphosphorylcholine[5]miltefosine (hexadecylphosphocholine, MT) analogs[6]phosphoric acid 2-trimethylamino-ethyl ester undec-10-enyl ester[7]uridine nucleolipid, (2′,3′-O-16-hentriacontanyliden-uridine-5′-phosphocholine, PUPC)[8]adenosine nucleoamphiphile, (2′,3′-O-16-hentriacontanyliden-adenosine-5′-phosphocholine, PAPC)[8]structurally related phospholipids which are either conformationally restricted or flexible[9]phosphatidylcholines[10][11]

SAFETY INFORMATION

Pictograms

GHS05

Signal Word

Danger

Hazard Statements

H314

Precautionary Statements

P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Supplementary Hazards

EUH014,EUH029

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

377953

--


form:
liquid

Quality Level:
200

impurities:
<10% 2-Chloro-1,3,2-dioxaphospholane

refractive index:
n20/D 1.45 (lit.)

bp:
89-91 °C/0.8 mmHg (lit.)

mp:
12-14 °C (neat) (lit.)

density:
1.55 g/mL at 25 °C (lit.)

storage temp.:
−20°C

SMILES string:
ClP1(=O)OCCO1

InChI:
1S/C2H4ClO3P/c3-7(4)5-1-2-6-7/h1-2H2

Img

Sigma Aldrich

377996

99.999% trace metals basis...


form:
liquid

Quality Level:
200

impurities:
__

refractive index:
n20/D 1.464 (lit.)

bp:
232 °C (lit.)

mp:
14-17 °C (lit.)

density:
0.96 g/mL at 20 °C (lit.)

storage temp.:
__

SMILES string:
CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C

InChI:
1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4

Img

Sigma Aldrich

377996

99.999% trace metals basis...


form:
liquid

Quality Level:
200

impurities:
__

refractive index:
n20/D 1.464 (lit.)

bp:
232 °C (lit.)

mp:
14-17 °C (lit.)

density:
0.96 g/mL at 20 °C (lit.)

storage temp.:
__

SMILES string:
CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C

InChI:
1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4

Img

Sigma Aldrich

377996

99.999% trace metals basis...


form:
liquid

Quality Level:
200

impurities:
__

refractive index:
n20/D 1.464 (lit.)

bp:
232 °C (lit.)

mp:
14-17 °C (lit.)

density:
0.96 g/mL at 20 °C (lit.)

storage temp.:
__

SMILES string:
CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C

InChI:
1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4