405957

Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite

98%

Manufacturer: Sigma Aldrich

CAS Number: 66470-81-3

Synonym(S): Tris(2H-perfluoro-2-propyl) phosphite

Select a Size

Pack Size SKU Availability Price
1 G 405957-1-G In Stock ₹ 10,424.48

405957 - 1 G

₹ 10,424.48

In Stock

Quantity

1

Base Price: ₹ 10,424.48

GST (18%): ₹ 1,876.406

Total Price: ₹ 12,300.886

Quality Level

100

Assay

98%

form

liquid

refractive index

n20/D 1.300 (lit.)

bp

130 °C (lit.)

density

1.69 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C(OP(OC(C(F)(F)F)C(F)(F)F)OC(C(F)(F)F)C(F)(F)F)C(F)(F)F

InChI

1S/C9H3F18O3P/c10-4(11,12)1(5(13,14)15)28-31(29-2(6(16,17)18)7(19,20)21)30-3(8(22,23)24)9(25,26)27/h1-3H

InChI key

MJOVEPJSFHDSOJ-UHFFFAOYSA-N

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Description

  • General description: Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite (tris(1,1,1,3,3,3-hexafluoroisopropyl) phosphite) is a sterically hindered, weakly σ-donating and strongly π-accepting ligand.[1] It can be prepared by the reaction of lithium salt of 1,1,1,3,3,3-hexafluoro-2-propoxide with PCl3.[2] It reacts with nucleosides to form deoxyribonucleoside 3′-bis(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite units.[3]
  • Application: Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite (tris(1,1,1,3,3,3-hexafluoroisopropyl) phosphite) may be used in the following processes:Preparation of new phosphonylating and coupling agents for the synthesis of oligodeoxyribonucleotides.[2]Preparation of nucleoside H-phosphonate units.[4]Synthesis of tetrakis(1,1,1,3,3,3-hexafluoroisopropoxy)(phenylthio)phosphorane by reacting with 1,1,1,3,3,3-hexafluoroisopropyl benzenesulfenate.[5]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Show Difference

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Sigma Aldrich

405957

98%...


Quality Level:
100

Assay:
98%

form:
liquid

refractive index:
n20/D 1.300 (lit.)

bp:
130 °C (lit.)

density:
1.69 g/mL at 25 °C (lit.)

SMILES string:
FC(F)(F)C(OP(OC(C(F)(F)F)C(F)(F)F)OC(C(F)(F)F)C(F)(F)F)C(F)(F)F

InChI:
1S/C9H3F18O3P/c10-4(11,12)1(5(13,14)15)28-31(29-2(6(16,17)18)7(19,20)21)30-3(8(22,23)24)9(25,26)27/h1-3H

InChI key:
MJOVEPJSFHDSOJ-UHFFFAOYSA-N

Img

Sigma Aldrich

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refractive index:
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bp:
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density:
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SMILES string:
CC(C)(C)[C@H]1COC(CC2=N[C@H](CO2)C(C)(C)C)=N1

InChI:
1S/C15H26N2O2/c1-14(2,3)10-8-18-12(16-10)7-13-17-11(9-19-13)15(4,5)6/h10-11H,7-9H2,1-6H3/t10-,11-/m1/s1

InChI key:
WCCCBUXURHZPQL-GHMZBOCLSA-N

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Sigma Aldrich

405973

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Assay:
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SMILES string:
C1OC(=N[C@H]1Cc2ccccc2)C3=N[C@H](CO3)Cc4ccccc4

InChI:
1S/C20H20N2O2/c1-3-7-15(8-4-1)11-17-13-23-19(21-17)20-22-18(14-24-20)12-16-9-5-2-6-10-16/h1-10,17-18H,11-14H2/t17-,18-/m0/s1

InChI key:
OIEQQWQZUYZCRJ-ROUUACIJSA-N

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Sigma Aldrich

405981

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SMILES string:
C(C1=N[C@@H]([C@@H](O1)c2ccccc2)c3ccccc3)C4=N[C@@H]([C@@H](O4)c5ccccc5)c6ccccc6

InChI:
1S/C31H26N2O2/c1-5-13-22(14-6-1)28-30(24-17-9-3-10-18-24)34-26(32-28)21-27-33-29(23-15-7-2-8-16-23)31(35-27)25-19-11-4-12-20-25/h1-20,28-31H,21H2/t28-,29-,30+,31+/m1/s1

InChI key:
BVEHHQYXICTXGR-VKONIRKNSA-N